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• W2945832816 abstract "Earth-abundant copper barium thioselenostannate, $mathrm{C}{mathrm{u}}_{2}mathrm{BaSn}{(mathrm{S},mathrm{Se})}_{4}$, absorbers have recently demonstrated promising optoelectronic and defect resistance properties for solar harvesting applications. The highest photovoltaic device efficiencies have been achieved in vacuum-based co-sputter deposited films, yet there is a tendency for a multilayer formation consisting of large, plateletlike surface grains and a smaller grain-sized underlayer (often accompanied by voids). In this work we use a combination of in situ and ex situ x-ray diffraction and scanning electron microscopy to unravel the coupling of phase evolution to film morphology. We find that Cu surface migration and associated Cu-rich phases play a defining role in determining the overall film structure." @default.
• W2945832816 created "2019-05-29" @default.
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• W2945832816 date "2019-05-15" @default.
• W2945832816 modified "2023-10-03" @default.
• W2945832816 title "Phase and film formation pathway for vacuum-deposited <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi mathvariant=normal>C</mml:mi><mml:msub><mml:mi mathvariant=normal>u</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mi>BaSn</mml:mi><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:mi mathvariant=normal>S</mml:mi><mml:mo>,</mml:mo><mml:mi>Se</mml:mi></mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math> absorber layers" @default.
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• W2945832816 doi "https://doi.org/10.1103/physrevmaterials.3.055402" @default.
• W2945832816 hasPublicationYear "2019" @default.
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