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- W2946092142 abstract "Abstract The complexes of gossypol with Fe 2+ were prepared by using methanol as solvent in the presence of CO 2 atmosphere. The results from FT‐IR spectra analysis indicated that the aromatic aldehyde groups in gossypol molecules were entirely involved in coordination with Fe 2+ . UV‐Vis absorption spectrum of the complexes in methanol solution displays blue‐shift in comparison with that of gossypol. Five compounds from the complexes were isolated by high performance liquid chromatography. The structures of the complexes are consistent with PM3 calculations. Two compounds were formed by coordination of gossypol with Fe 2+ at 1:2 molar ratio, other three compounds were formed by chelation of gossypol with Fe 2+ at molar ratio by 1:1, 1:3, and 1:4 respectively." @default.
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- W2946092142 date "2019-05-17" @default.
- W2946092142 modified "2023-10-16" @default.
- W2946092142 title "Structures of Complexes of Gossypol with Ferrous Sulfate Based on High‐Performance Liquid Chromatography Separation, Spectroscopic Analysis, and PM3 calculations" @default.
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- W2946092142 doi "https://doi.org/10.1002/slct.201803967" @default.
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