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• W2947029789 endingPage "327" @default.
• W2947029789 startingPage "316" @default.
• W2947029789 abstract "Abstract Currently, the occurrence of ciprofloxacin in the water environment has raised serious concerns. For utilizing the sunlight for degradation of ciprofloxacin it is important to develop visible light semiconductor photocatalysts with high catalytic activity. In this paper, Zn-doped Cu2O particles were prepared by a solvothermal method. The effects of Zn-doped on the structures and performances of Cu2O were examined via XRD, XPS, SEM, TEM, BET, and UV–Vis techniques. The photocatalytic mechanism and the factors responsible for the enhanced photocatalytic performance of the Zn-doped Cu2O were investigated. The main intermediate products of the photocatalytic degradation were elucidated using HPLC-MS/MS analysis. Frontier electron densities were used to predict the reaction sites of ciprofloxacin. The results indicate that the prepared samples have high purities, and the Cu2O, R1, R2, and R3-Cu2O exhibit dodecahedron, polyhedral, octahedral, and hexahedral morphologies, respectively. Compared with pure Cu2O, the specific surface areas of the Zn-doped Cu2O increased, the absorption intensity improved significantly in the visible light range, and the band gap is greater than that of the undoped Cu2O. The fitting resistance values decreased significantly, and the transfer and separation efficiencies of the photogenerated electrons and holes were improved. Among the samples, R2-Cu2O has the best photocatalytic performance and reusability. 94.6% of ciprofloxacin was degraded in presence of R2-Cu2O. After 5 cycles, the degradation percentage still exceeded 91%. The degradation of ciprofloxacin begins with direct attack of the photogenerated holes and the addition of hydroxyl radicals. Two possible degradation pathways from the cleavage of the piperazine ring and the decarboxylation of the quinolonic ring were suggested by combining the experimental data with the theoretical calculations of the frontier electron densities. This research work provides an insight into the mechanism and pathways of ciprofloxacin degradation by Zn-doped Cu2O, and opens-up a new opportunity for the treatment of ciprofloxacin-containing wastewater using semiconductor photocatalytic oxidation technology." @default.
• W2947029789 created "2019-06-07" @default.
• W2947029789 creator A5017041253 @default.
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• W2947029789 creator A5085105232 @default.
• W2947029789 creator A5085317176 @default.
• W2947029789 creator A5088469881 @default.
• W2947029789 date "2019-10-01" @default.
• W2947029789 modified "2023-10-17" @default.
• W2947029789 title "Photocatalytic degradation of ciprofloxacin using Zn-doped Cu2O particles: Analysis of degradation pathways and intermediates" @default.
• W2947029789 cites W1546112631 @default.
• W2947029789 cites W1976683768 @default.
• W2947029789 cites W1981899091 @default.
• W2947029789 cites W1987651401 @default.
• W2947029789 cites W1993714799 @default.
• W2947029789 cites W1998173492 @default.
• W2947029789 cites W1998207372 @default.
• W2947029789 cites W2001098288 @default.
• W2947029789 cites W2001305316 @default.
• W2947029789 cites W2006401799 @default.
• W2947029789 cites W2018593167 @default.
• W2947029789 cites W2020530692 @default.
• W2947029789 cites W2021502427 @default.
• W2947029789 cites W2023251671 @default.
• W2947029789 cites W2026608207 @default.
• W2947029789 cites W2036481359 @default.
• W2947029789 cites W2041491000 @default.
• W2947029789 cites W2049015639 @default.
• W2947029789 cites W2049588534 @default.
• W2947029789 cites W2049885716 @default.
• W2947029789 cites W2052846349 @default.
• W2947029789 cites W2053304474 @default.
• W2947029789 cites W2054726049 @default.
• W2947029789 cites W2058108555 @default.
• W2947029789 cites W2077796804 @default.
• W2947029789 cites W2080197689 @default.
• W2947029789 cites W2087200161 @default.
• W2947029789 cites W2087633157 @default.
• W2947029789 cites W2090114550 @default.
• W2947029789 cites W2091589336 @default.
• W2947029789 cites W2093076236 @default.
• W2947029789 cites W2094369457 @default.
• W2947029789 cites W2100403667 @default.
• W2947029789 cites W2105761236 @default.
• W2947029789 cites W2116067171 @default.
• W2947029789 cites W2166828764 @default.
• W2947029789 cites W2169407189 @default.
• W2947029789 cites W2191941098 @default.
• W2947029789 cites W2236556070 @default.
• W2947029789 cites W2261832167 @default.
• W2947029789 cites W2282926382 @default.
• W2947029789 cites W2310325129 @default.
• W2947029789 cites W2318373450 @default.
• W2947029789 cites W2318579790 @default.
• W2947029789 cites W2320968654 @default.
• W2947029789 cites W2334428710 @default.
• W2947029789 cites W2338308945 @default.
• W2947029789 cites W2399889263 @default.
• W2947029789 cites W2410896784 @default.
• W2947029789 cites W2492431803 @default.
• W2947029789 cites W2494304046 @default.
• W2947029789 cites W2554186998 @default.
• W2947029789 cites W2562404168 @default.
• W2947029789 cites W2585604216 @default.
• W2947029789 cites W2595802862 @default.
• W2947029789 cites W2606079782 @default.
• W2947029789 cites W2609303905 @default.
• W2947029789 cites W2613102884 @default.
• W2947029789 cites W2616885682 @default.
• W2947029789 cites W2734736418 @default.
• W2947029789 cites W2736350645 @default.
• W2947029789 cites W2737396709 @default.
• W2947029789 cites W2738291244 @default.
• W2947029789 cites W2739606443 @default.
• W2947029789 cites W2748075725 @default.
• W2947029789 cites W2751304677 @default.
• W2947029789 cites W2761211523 @default.
• W2947029789 cites W2763816391 @default.
• W2947029789 cites W2766325522 @default.
• W2947029789 cites W2766654538 @default.
• W2947029789 cites W2769208710 @default.
• W2947029789 cites W2769922566 @default.
• W2947029789 cites W2771209793 @default.
• W2947029789 cites W2772202977 @default.
• W2947029789 cites W2775549478 @default.
• W2947029789 cites W2790108053 @default.
• W2947029789 cites W2791458801 @default.
• W2947029789 cites W2792437860 @default.
• W2947029789 cites W2793066960 @default.
• W2947029789 cites W2799383115 @default.
• W2947029789 cites W2799483626 @default.
• W2947029789 cites W2800046105 @default.
• W2947029789 cites W2800428066 @default.
• W2947029789 cites W2800539326 @default.
• W2947029789 cites W2801105853 @default.
• W2947029789 cites W2893196103 @default.

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