FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2947058239> ?p ?o ?g. }

• W2947058239 endingPage "9936" @default.
• W2947058239 startingPage "9928" @default.
• W2947058239 abstract "We present the synthesis and magnetic characterization of a polycrystalline sample of the 6H-perovskite Ba3CeRu2O9, which consists of Ru dimers based on face-sharing RuO6 octahedra. Our low-temperature magnetic susceptibility, magnetization, and neutron powder diffraction results reveal a nonmagnetic singlet ground state for the dimers. Inelastic neutron scattering, infrared spectroscopy, and the magnetic susceptibility over a wide temperature range are best explained by a molecular orbital model with a zero-field splitting parameter D = 85 meV for the Stot = 1 electronic ground-state multiplet. This large value is likely due to strong mixing between this ground-state multiplet and low-lying excited multiplets, arising from a sizable spin molecular orbital coupling combined with an axial distortion of the Ru2O9 units. Although the positive sign for the splitting ensures that Ba3CeRu2O9 is not a single molecule magnet, our work suggests that the search for these interesting materials should be extended beyond Ba3CeRu2O9 to other molecular magnets based on metal-metal bonding." @default.
• W2947058239 created "2019-06-07" @default.
• W2947058239 creator A5010044705 @default.
• W2947058239 creator A5017273433 @default.
• W2947058239 creator A5041716995 @default.
• W2947058239 creator A5049054121 @default.
• W2947058239 creator A5061163951 @default.
• W2947058239 creator A5073212256 @default.
• W2947058239 creator A5073741720 @default.
• W2947058239 creator A5075360660 @default.
• W2947058239 creator A5089162535 @default.
• W2947058239 date "2019-05-28" @default.
• W2947058239 modified "2023-10-14" @default.
• W2947058239 title "Large Positive Zero-Field Splitting in the Cluster Magnet Ba₃CeRu₂O₉" @default.
• W2947058239 cites W1806198120 @default.
• W2947058239 cites W1889725240 @default.
• W2947058239 cites W1972331312 @default.
• W2947058239 cites W1976095558 @default.
• W2947058239 cites W1980905694 @default.
• W2947058239 cites W1982482676 @default.
• W2947058239 cites W1990654323 @default.
• W2947058239 cites W1994942857 @default.
• W2947058239 cites W1999624341 @default.
• W2947058239 cites W2007931943 @default.
• W2947058239 cites W2012138713 @default.
• W2947058239 cites W2012202243 @default.
• W2947058239 cites W2016374839 @default.
• W2947058239 cites W2018290412 @default.
• W2947058239 cites W2022256070 @default.
• W2947058239 cites W2022490741 @default.
• W2947058239 cites W2028953935 @default.
• W2947058239 cites W2033381590 @default.
• W2947058239 cites W2042002692 @default.
• W2947058239 cites W2047922110 @default.
• W2947058239 cites W2051173396 @default.
• W2947058239 cites W2054608276 @default.
• W2947058239 cites W2059833072 @default.
• W2947058239 cites W2066793460 @default.
• W2947058239 cites W2068621667 @default.
• W2947058239 cites W2070150426 @default.
• W2947058239 cites W2071048660 @default.
• W2947058239 cites W2071236931 @default.
• W2947058239 cites W2074688286 @default.
• W2947058239 cites W2077836577 @default.
• W2947058239 cites W2082955660 @default.
• W2947058239 cites W2083196193 @default.
• W2947058239 cites W2087266110 @default.
• W2947058239 cites W2089740902 @default.
• W2947058239 cites W2098269921 @default.
• W2947058239 cites W2136730118 @default.
• W2947058239 cites W2146099614 @default.
• W2947058239 cites W2146695448 @default.
• W2947058239 cites W2161362684 @default.
• W2947058239 cites W2219740651 @default.
• W2947058239 cites W2286530637 @default.
• W2947058239 cites W2287319506 @default.
• W2947058239 cites W2312382593 @default.
• W2947058239 cites W2332018527 @default.
• W2947058239 cites W2332402427 @default.
• W2947058239 cites W2403530681 @default.
• W2947058239 cites W2565182904 @default.
• W2947058239 cites W2605199984 @default.
• W2947058239 cites W2789870702 @default.
• W2947058239 cites W2891343486 @default.
• W2947058239 cites W2892237633 @default.
• W2947058239 cites W2896968078 @default.
• W2947058239 cites W3098983424 @default.
• W2947058239 cites W3099191727 @default.
• W2947058239 cites W3100339973 @default.
• W2947058239 cites W3102421901 @default.
• W2947058239 doi "https://doi.org/10.1021/jacs.9b03389" @default.
• W2947058239 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31136169" @default.
• W2947058239 hasPublicationYear "2019" @default.
• W2947058239 type Work @default.
• W2947058239 sameAs 2947058239 @default.
• W2947058239 citedByCount "12" @default.
• W2947058239 countsByYear W29470582392020 @default.
• W2947058239 countsByYear W29470582392021 @default.
• W2947058239 countsByYear W29470582392022 @default.
• W2947058239 countsByYear W29470582392023 @default.
• W2947058239 crossrefType "journal-article" @default.
• W2947058239 hasAuthorship W2947058239A5010044705 @default.
• W2947058239 hasAuthorship W2947058239A5017273433 @default.
• W2947058239 hasAuthorship W2947058239A5041716995 @default.
• W2947058239 hasAuthorship W2947058239A5049054121 @default.
• W2947058239 hasAuthorship W2947058239A5061163951 @default.
• W2947058239 hasAuthorship W2947058239A5073212256 @default.
• W2947058239 hasAuthorship W2947058239A5073741720 @default.
• W2947058239 hasAuthorship W2947058239A5075360660 @default.
• W2947058239 hasAuthorship W2947058239A5089162535 @default.
• W2947058239 hasBestOaLocation W29470582392 @default.
• W2947058239 hasConcept C104015590 @default.
• W2947058239 hasConcept C115260700 @default.
• W2947058239 hasConcept C115624301 @default.
• W2947058239 hasConcept C121332964 @default.
• W2947058239 hasConcept C122290 @default.
• W2947058239 hasConcept C1276947 @default.
• W2947058239 hasConcept C133871045 @default.

• next