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• W2947075724 abstract "The nickel-catalyzed cyclization of bisphosphine derivatives to form various phosphacycles is reported. The reaction proceeds via the cleavage of two carbon-phosphorus bonds of the bisphosphine. Unlike the previously reported palladium catalysts, the use of nickel as a catalyst allows for the cyclization that requires C(alkyl)-P bond cleavage. A phospha-nickelacycle intermediate was successfully isolated and characterized by X-ray crystallography." @default.
• W2947075724 created "2019-06-07" @default.
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• W2947075724 date "2019-05-22" @default.
• W2947075724 modified "2023-10-18" @default.
• W2947075724 title "Cyclization of Bisphosphines to Phosphacycles via the Cleavage of Two Carbon–Phosphorus Bonds by Nickel Catalysis" @default.
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• W2947075724 doi "https://doi.org/10.1021/acs.orglett.9b01355" @default.
• W2947075724 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31117707" @default.
• W2947075724 hasPublicationYear "2019" @default.
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