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- W2947122106 abstract "To overcome the weak carbon dioxide (CO 2 ) conversion ability of Zn‐Co double metal cyanide (DMC) catalyst, zinc glutarate (ZnGA) catalyst was introduced into the DMC catalytic system and applied for the synthesis of oligo (propylene‐carbonate) diols. The DMC/ZnGA composite catalyst (mass ratio = 10:1) exhibited an excellent synergistic effect which had enhanced CO 2 activation ability, high yield and good selectivity. In copolymerization process, ZnGA catalyst not only provided activated CO 2 for DMC catalyst, but also transferred the propagating chain with more alternating structures to DMC catalyst. Both of the two effects increased the carbonate content in the final products. Overall, DMC catalyst dedicated to the polymer chain growth, while the increased CO 2 conversion mainly attributed to ZnGA catalyst. Oligo (propylene‐carbonate) diols with carbonate unit content of 45.1 mol%, Mn of 1228 g/mol, W PC of 4.3 wt% and high yield of 1689 g/g cat was obtained." @default.
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- W2947122106 date "2019-05-29" @default.
- W2947122106 modified "2023-10-16" @default.
- W2947122106 title "Facile preparation and synergy study of DMC/ZnGA composite catalyst for the synthesis of oligo (propylene‐carbonate) diols" @default.
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- W2947122106 doi "https://doi.org/10.1002/aoc.4999" @default.
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