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- W2947133312 abstract "Heteroarenes and arenes that contain electron-withdrawing groups are chlorinated in good to excellent yields (scalable to gram scale) using trichloroisocyanuric acid (TCCA) and catalytic Brilliant Green (BG). Visible-light activation of BG serves to amplify the electrophilic nature of TCCA, providing a mild alternative approach to acid-promoted chlorination of deactivated (hetero)aromatic substrates. The utility of the TCCA/BG system is demonstrated through comparison to other chlorinating reagents and by the chlorination of pharmaceuticals including caffeine, lidocaine, and phenazone." @default.
- W2947133312 created "2019-06-07" @default.
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- W2947133312 date "2019-05-29" @default.
- W2947133312 modified "2023-10-01" @default.
- W2947133312 title "Amplification of Trichloroisocyanuric Acid (TCCA) Reactivity for Chlorination of Arenes and Heteroarenes via Catalytic Organic Dye Activation" @default.
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- W2947133312 doi "https://doi.org/10.1021/acs.orglett.9b01414" @default.
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