Matches in SemOpenAlex for { <https://semopenalex.org/work/W2947196070> ?p ?o ?g. }
- W2947196070 endingPage "485" @default.
- W2947196070 startingPage "478" @default.
- W2947196070 abstract "The redox flow battery is a leading candidate to supply society with large-scale energy storage. In the category of aqueous organic redox flow batteries, 9,10-anthraquinone-2,7-disulfonic acid (AQDS) is considered a top-performing molecule and shows ideal electrochemical behavior at low concentrations around 1 mM. However, its behavior at higher concentrations was rarely studied. In this work, the correlation between concentration and electrochemical capacity is evaluated for AQDS in 1 M H2SO4 and 1 M alkaline sodium carbonate buffer, employing cyclic voltammetry, rotating disk electrode voltammetry and diffusion NMR. It was found that an electrochemically inactive dimer was formed by the unreduced AQDS molecules, with dimerization equilibrium constants determined to be K = 5 M−1 for the acidic electrolyte and 8 M−1 for the alkaline one, significantly inhibiting full electrochemical utilization of the system. However, upon reduction of the bulk material, the dimerization will shift in favor of monomer or quinhydrone formation, possibly alleviating the impediment to reduction. Finally, it was found that the dimerization could be decreased slightly by increasing the temperature of the system." @default.
- W2947196070 created "2019-06-07" @default.
- W2947196070 creator A5017707988 @default.
- W2947196070 creator A5042249105 @default.
- W2947196070 creator A5047614856 @default.
- W2947196070 creator A5055692639 @default.
- W2947196070 creator A5061048169 @default.
- W2947196070 date "2019-09-01" @default.
- W2947196070 modified "2023-10-16" @default.
- W2947196070 title "Dimerization of 9,10-anthraquinone-2,7-Disulfonic acid (AQDS)" @default.
- W2947196070 cites W1906560025 @default.
- W2947196070 cites W1964051967 @default.
- W2947196070 cites W1996417284 @default.
- W2947196070 cites W2001036538 @default.
- W2947196070 cites W2015055518 @default.
- W2947196070 cites W2059306046 @default.
- W2947196070 cites W2061505993 @default.
- W2947196070 cites W2063196204 @default.
- W2947196070 cites W2066863258 @default.
- W2947196070 cites W2067936194 @default.
- W2947196070 cites W2091859626 @default.
- W2947196070 cites W2092826347 @default.
- W2947196070 cites W2107268704 @default.
- W2947196070 cites W2111003787 @default.
- W2947196070 cites W2122408573 @default.
- W2947196070 cites W2125661173 @default.
- W2947196070 cites W2135086200 @default.
- W2947196070 cites W2135999176 @default.
- W2947196070 cites W2186629838 @default.
- W2947196070 cites W2210312065 @default.
- W2947196070 cites W2328269614 @default.
- W2947196070 cites W2399671312 @default.
- W2947196070 cites W2483976794 @default.
- W2947196070 cites W2508082070 @default.
- W2947196070 cites W2520322574 @default.
- W2947196070 cites W2521112071 @default.
- W2947196070 cites W2533840362 @default.
- W2947196070 cites W2554373926 @default.
- W2947196070 cites W2556221011 @default.
- W2947196070 cites W2562390458 @default.
- W2947196070 cites W2565606293 @default.
- W2947196070 cites W2587300670 @default.
- W2947196070 cites W2593754560 @default.
- W2947196070 cites W2598085257 @default.
- W2947196070 cites W2598862204 @default.
- W2947196070 cites W2605793770 @default.
- W2947196070 cites W2616367498 @default.
- W2947196070 cites W2623582797 @default.
- W2947196070 cites W2769655478 @default.
- W2947196070 cites W2770491954 @default.
- W2947196070 cites W2883313923 @default.
- W2947196070 cites W2904080980 @default.
- W2947196070 doi "https://doi.org/10.1016/j.electacta.2019.05.134" @default.
- W2947196070 hasPublicationYear "2019" @default.
- W2947196070 type Work @default.
- W2947196070 sameAs 2947196070 @default.
- W2947196070 citedByCount "37" @default.
- W2947196070 countsByYear W29471960702019 @default.
- W2947196070 countsByYear W29471960702020 @default.
- W2947196070 countsByYear W29471960702021 @default.
- W2947196070 countsByYear W29471960702022 @default.
- W2947196070 countsByYear W29471960702023 @default.
- W2947196070 crossrefType "journal-article" @default.
- W2947196070 hasAuthorship W2947196070A5017707988 @default.
- W2947196070 hasAuthorship W2947196070A5042249105 @default.
- W2947196070 hasAuthorship W2947196070A5047614856 @default.
- W2947196070 hasAuthorship W2947196070A5055692639 @default.
- W2947196070 hasAuthorship W2947196070A5061048169 @default.
- W2947196070 hasConcept C147789679 @default.
- W2947196070 hasConcept C17525397 @default.
- W2947196070 hasConcept C178790620 @default.
- W2947196070 hasConcept C179104552 @default.
- W2947196070 hasConcept C184651966 @default.
- W2947196070 hasConcept C185592680 @default.
- W2947196070 hasConcept C2777596839 @default.
- W2947196070 hasConcept C2777869211 @default.
- W2947196070 hasConcept C2778913731 @default.
- W2947196070 hasConcept C2779546866 @default.
- W2947196070 hasConcept C2779603750 @default.
- W2947196070 hasConcept C2779651331 @default.
- W2947196070 hasConcept C32909587 @default.
- W2947196070 hasConcept C52859227 @default.
- W2947196070 hasConcept C55904794 @default.
- W2947196070 hasConcept C68801617 @default.
- W2947196070 hasConceptScore W2947196070C147789679 @default.
- W2947196070 hasConceptScore W2947196070C17525397 @default.
- W2947196070 hasConceptScore W2947196070C178790620 @default.
- W2947196070 hasConceptScore W2947196070C179104552 @default.
- W2947196070 hasConceptScore W2947196070C184651966 @default.
- W2947196070 hasConceptScore W2947196070C185592680 @default.
- W2947196070 hasConceptScore W2947196070C2777596839 @default.
- W2947196070 hasConceptScore W2947196070C2777869211 @default.
- W2947196070 hasConceptScore W2947196070C2778913731 @default.
- W2947196070 hasConceptScore W2947196070C2779546866 @default.
- W2947196070 hasConceptScore W2947196070C2779603750 @default.
- W2947196070 hasConceptScore W2947196070C2779651331 @default.
- W2947196070 hasConceptScore W2947196070C32909587 @default.
- W2947196070 hasConceptScore W2947196070C52859227 @default.