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- W2947580913 abstract "The control of thermal expansion represents a challenge in materials design. This work shows that the length of the lattice parameter is a key element for controlling thermal expansion. By varying the lattice parameter through external pressure, chemical or other methods, the single-well potential energy of the polyhedra rotations (or of the atomic transverse vibrations) responsible for negative thermal expansion (NTE), can be turned into a quartic anharmonic potential or into a double-well potential, thus enhancing or suppressing the NTE, respectively. This result applied to framework materials should be taken into account to overcome the challenge of controlling thermal expansion." @default.
- W2947580913 created "2019-06-07" @default.
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- W2947580913 date "2019-05-31" @default.
- W2947580913 modified "2023-10-16" @default.
- W2947580913 title "On the switching between negative and positive thermal expansion in framework materials" @default.
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- W2947580913 doi "https://doi.org/10.1080/21663831.2019.1621957" @default.
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