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• W2947624426 abstract "The thermal oxidation of DGEBA-DDS (bisphenol A diglycidyl ether + 4,4′-diaminodiphenyl sulfone) and TGMDA-DDS (4,4′-methylenebis(N,N-diglycidylaniline) + 4,4′-diaminodiphenyl sulfone) was performed at 80, 120, and 200 °C and was monitored by FTIR. Oxidation was shown to generate amides and carbonyls. Comparisons were done with model systems displaying some common reactive groups, which highlighted the predominating role of methylene in α position of ether in DGEBA-DDS and methylene in α position of nitrogen hold by TGMDA in TGMDA-DDS. The participation of CH2 in α position of DDS hardener group seems to depend on the temperature and decrease when lowering it. The oxidation of such complex systems must hence be described by a co-oxidation model where each kind of reactive sites is described by its own set of kinetic constants." @default.
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• W2947624426 date "2019-08-01" @default.
• W2947624426 modified "2023-10-17" @default.
• W2947624426 title "Thermal oxidation of aromatic epoxy-diamine networks" @default.
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• W2947624426 doi "https://doi.org/10.1016/j.polymdegradstab.2019.05.030" @default.
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