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- W2947746512 abstract "The adsorption of thiocyanate (SCN−) from water is a challenging and urgent task. In this work, a cationic metal-organic framework [Ag-4, 4′-bipy+] [NO3−] (SBN) was successfully synthesized for the highly efficient removal of SCN−. A series of characterization results show that SBN has good hydrolytic stability and thermal stability. SBN shows higher adsorption capacity (174.2 mg g−1) for SCN− than any other previous adsorbents. Kinetic study shows that adsorption equilibrium can be achieved within 10 min. SBN has good stability in the range of pH 2–10, and the adsorption capacity is immobile with the change of pH. In addition, SBN has a good selectivity for SCN− in the presence of other ions. The increased concentration of NO3− during the adsorption verified that the mechanism of SBN for SCN− removal is ion exchange, which formed [Ag-4, 4′-bipy+] [SCN−] (SBS). The low Gibb's energy (ΔrG(T)) indicates that the ion exchange process is thermodynamically spontaneous. Elution experiments showed that no anions could successfully elute SCN−. This work used a metal-organic framework for the adsorption of SCN− for the first time, revealing a new method for the adsorption and immobilization of SCN− in aqueous solutions." @default.
- W2947746512 created "2019-06-07" @default.
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- W2947746512 date "2019-10-01" @default.
- W2947746512 modified "2023-09-25" @default.
- W2947746512 title "A cationic metal-organic framework for the highly efficient removal of thiocyanate from water" @default.
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- W2947746512 doi "https://doi.org/10.1016/j.micromeso.2019.05.027" @default.
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