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- W2947981332 abstract "The application of skeletal numbers has made it far much easier to categorize and analyze a wide range of clusters very quickly according to the 4N series method. It has been revealed that the clusters ranging from mono-to multi-skeletal elements comprise of two shells simply referred to as the inner (D) shell and the outer shell (C). A symbol to represent this duality concept has been introduced as the double capping parameter K* = Cy+Dz, where y+z = n, the number of skeletal elements in a cluster. Depending upon the cluster being analyzed, both C and could represent capping skeletal elements or in some cases, D could refer to capping electrons in dozen pairs. In other cases the C symbol could represent the missing skeletal elements for a cluster in order to achieve a CLOSO (fragment that follows S=4n+2 series) configuration. In order to demonstrate the double capping nature of clusters, about 40 clusters were categorized more than 30 of which were bi-metallic golden clusters. All of them were found to be capped with both C and D comprising of skeletal elements. The D elements are capped on the GENESIS ELECTRONS given by VE0=2z+2 electrons in the inner shell while the C elements are capped on top of the D closo elements. More examples of clusters were readily categorized into CLAN SERIES. A new equation for calculating the cluster valence electrons was derived as VE= 12y+14z+2 from K* = Cy+Dz. The calculated VE value was found to be the same as the one VF calculated directly from the cluster formula. The new equation for calculating cluster valence electrons is on of the six equations which can eaily be applied to calculate the cluster valence electrons of clusters and chemical elements of the periodic table except lanthanides and actinides." @default.
- W2947981332 created "2019-06-07" @default.
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- W2947981332 date "2019-01-01" @default.
- W2947981332 modified "2023-09-23" @default.
- W2947981332 title "The Double Capping Phenomenon of Chemical Clusters" @default.
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