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- W2948024102 abstract "The incorporation of a hexadecyl group on imidazolium, pyridinium, and pyrrolidinium scaffolds produces low-molecular-weight ionic organogelators that can gel several types of ionic liquids, deep eutectic solvents (DESs), and several molecular organic solvents. Minimum gelator concentrations fall in the 0.9–15.0% (w/v) range, with the lower end of the gelator concentrations observed in the gelation of DESs. On the basis of polarized optical microscopy, differential scanning calorimetry, and X-ray data, crystallization of these salts appear to produce high-surface-area crystals, which generate sufficiently stable three-dimensional networks that are capable of trapping the solvent molecules. Importantly, the nature of the fluid component of the gel appears to have a profound effect on the morphology of the crystallized organogelators. On the other hand, the organogelators appeared to modulate phase transitions of the liquids." @default.
- W2948024102 created "2019-06-07" @default.
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- W2948024102 date "2019-05-29" @default.
- W2948024102 modified "2023-10-14" @default.
- W2948024102 title "Hexadecyl-Containing Organic Salts as Novel Organogelators for Ionic, Eutectic, and Molecular Liquids" @default.
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- W2948024102 doi "https://doi.org/10.1021/acsomega.9b00038" @default.
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