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- W2948061610 abstract "Abstract Dendrimers are homostructural and highly branched macromolecules with unique dendritic effects and extensive use in multidisciplinary fields. Although thousands of dendrimers have been synthesized in solution, the on-surface synthetic protocol for planar dendrimers has never been explored, limiting the elucidation of the mechanism of dendritic effects at the single-molecule level. Herein, we describe an on-surface synthetic approach to planar dendrimers, in which exogenous palladium is used as a catalyst to address the divergent cross-coupling of aryl bromides with isocyanides. This reaction enables one aryl bromide to react with two isocyanides in sequential steps to generate the divergently grown product composed of a core and two branches with high selectivity and reactivity. Then, a dendron with four branches and dendrimers with eight or twelve branches in the outermost shell are synthesized on Au(111). This work opens the door for the on-surface synthesis of various planar dendrimers and relevant macromolecular systems." @default.
- W2948061610 created "2019-06-14" @default.
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- W2948061610 date "2019-06-03" @default.
- W2948061610 modified "2023-10-12" @default.
- W2948061610 title "On-surface synthesis of planar dendrimers via divergent cross-coupling reaction" @default.
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- W2948061610 doi "https://doi.org/10.1038/s41467-019-10407-6" @default.
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