Matches in SemOpenAlex for { <https://semopenalex.org/work/W2948181036> ?p ?o ?g. }
- W2948181036 endingPage "7259" @default.
- W2948181036 startingPage "7251" @default.
- W2948181036 abstract "We report a mild approach to the synthesis of difluoro(aryl)-λ3-iodanes (aryl-IF2 compounds) and tetrafluoro(aryl)-λ5-iodanes (aryl-IF4 compounds) using trichloroisocyanuric acid (TCICA) and potassium fluoride (KF). Under these reaction conditions, selective access to either the I(iii)- or I(v)-derivatives is predictable based solely on the substitution pattern of the iodoarene starting material. Moreover, the discovery of this TCICA/KF approach prompted detailed dynamic NMR, kinetic, computational, and crystallographic studies on the relationship between the IF2 group and the ortho-substituents on carefully designed probe molecules. It was during these experiments that the role of the ortho-substituent in inhibiting further oxidative fluorination of I(iii)-compounds to I(v)-compounds during the reaction with TCICA and KF was revealed. Additionally, a notable exception to this empirical trend is discussed herein." @default.
- W2948181036 created "2019-06-14" @default.
- W2948181036 creator A5004962300 @default.
- W2948181036 creator A5025187437 @default.
- W2948181036 creator A5028210233 @default.
- W2948181036 creator A5035779885 @default.
- W2948181036 creator A5039255382 @default.
- W2948181036 creator A5039999799 @default.
- W2948181036 creator A5062505975 @default.
- W2948181036 creator A5066108937 @default.
- W2948181036 creator A5073517394 @default.
- W2948181036 creator A5086705545 @default.
- W2948181036 creator A5091496919 @default.
- W2948181036 date "2019-01-01" @default.
- W2948181036 modified "2023-10-14" @default.
- W2948181036 title "Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(<scp>iii</scp>)- and I(<scp>v</scp>)-fluorides" @default.
- W2948181036 cites W1497755155 @default.
- W2948181036 cites W1973011588 @default.
- W2948181036 cites W1976457818 @default.
- W2948181036 cites W1994546424 @default.
- W2948181036 cites W1999434893 @default.
- W2948181036 cites W2001350277 @default.
- W2948181036 cites W2003399018 @default.
- W2948181036 cites W2009008810 @default.
- W2948181036 cites W2010349350 @default.
- W2948181036 cites W2036620431 @default.
- W2948181036 cites W2037084723 @default.
- W2948181036 cites W2041423216 @default.
- W2948181036 cites W2053249723 @default.
- W2948181036 cites W2054678170 @default.
- W2948181036 cites W2059722577 @default.
- W2948181036 cites W2061235528 @default.
- W2948181036 cites W2069006374 @default.
- W2948181036 cites W2074840691 @default.
- W2948181036 cites W2076119002 @default.
- W2948181036 cites W2087313629 @default.
- W2948181036 cites W2088636378 @default.
- W2948181036 cites W2094281871 @default.
- W2948181036 cites W2107581398 @default.
- W2948181036 cites W2112850441 @default.
- W2948181036 cites W2116488816 @default.
- W2948181036 cites W2121964985 @default.
- W2948181036 cites W2127999795 @default.
- W2948181036 cites W2167283616 @default.
- W2948181036 cites W2173312883 @default.
- W2948181036 cites W2177079132 @default.
- W2948181036 cites W2267475013 @default.
- W2948181036 cites W2317946178 @default.
- W2948181036 cites W2319902168 @default.
- W2948181036 cites W2323481761 @default.
- W2948181036 cites W2332086101 @default.
- W2948181036 cites W2336820549 @default.
- W2948181036 cites W2740700471 @default.
- W2948181036 cites W2777881448 @default.
- W2948181036 cites W2904874709 @default.
- W2948181036 cites W2910004101 @default.
- W2948181036 cites W2952450242 @default.
- W2948181036 cites W3004630337 @default.
- W2948181036 cites W4241247458 @default.
- W2948181036 doi "https://doi.org/10.1039/c9sc02162k" @default.
- W2948181036 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6685355" @default.
- W2948181036 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31588294" @default.
- W2948181036 hasPublicationYear "2019" @default.
- W2948181036 type Work @default.
- W2948181036 sameAs 2948181036 @default.
- W2948181036 citedByCount "21" @default.
- W2948181036 countsByYear W29481810362019 @default.
- W2948181036 countsByYear W29481810362020 @default.
- W2948181036 countsByYear W29481810362021 @default.
- W2948181036 countsByYear W29481810362022 @default.
- W2948181036 crossrefType "journal-article" @default.
- W2948181036 hasAuthorship W2948181036A5004962300 @default.
- W2948181036 hasAuthorship W2948181036A5025187437 @default.
- W2948181036 hasAuthorship W2948181036A5028210233 @default.
- W2948181036 hasAuthorship W2948181036A5035779885 @default.
- W2948181036 hasAuthorship W2948181036A5039255382 @default.
- W2948181036 hasAuthorship W2948181036A5039999799 @default.
- W2948181036 hasAuthorship W2948181036A5062505975 @default.
- W2948181036 hasAuthorship W2948181036A5066108937 @default.
- W2948181036 hasAuthorship W2948181036A5073517394 @default.
- W2948181036 hasAuthorship W2948181036A5086705545 @default.
- W2948181036 hasAuthorship W2948181036A5091496919 @default.
- W2948181036 hasBestOaLocation W29481810361 @default.
- W2948181036 hasConcept C155647269 @default.
- W2948181036 hasConcept C178790620 @default.
- W2948181036 hasConcept C179104552 @default.
- W2948181036 hasConcept C185592680 @default.
- W2948181036 hasConcept C21951064 @default.
- W2948181036 hasConcept C2778689049 @default.
- W2948181036 hasConcept C2780263894 @default.
- W2948181036 hasConcept C2780828025 @default.
- W2948181036 hasConcept C2781005040 @default.
- W2948181036 hasConcept C2781076698 @default.
- W2948181036 hasConcept C32909587 @default.
- W2948181036 hasConceptScore W2948181036C155647269 @default.
- W2948181036 hasConceptScore W2948181036C178790620 @default.
- W2948181036 hasConceptScore W2948181036C179104552 @default.
- W2948181036 hasConceptScore W2948181036C185592680 @default.