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- W2948560200 abstract "A three-component reaction between terminal alkyne, α-diazo amide, and isatin ketimine is realized by utilizing copper catalysis. A series of alkynyl-containing 3,3-disubstituted oxindoles were synthesized with high efficiency and diastereoselectivity under mild reaction conditions. This transformation is proposed to proceed through a Mannich-type trapping of an alkynoate copper intermediate derived from terminal alkyne and copper carbene species." @default.
- W2948560200 created "2019-06-14" @default.
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- W2948560200 date "2019-06-03" @default.
- W2948560200 modified "2023-10-13" @default.
- W2948560200 title "Cu(I)-Catalyzed Three-Component Reaction of α-Diazo Amide with Terminal Alkyne and Isatin Ketimine via Electrophilic Trapping of Active Alkynoate-Copper Intermediate" @default.
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- W2948560200 doi "https://doi.org/10.1021/acs.orglett.9b01470" @default.
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