FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2948652296> ?p ?o ?g. }

• W2948652296 endingPage "5324" @default.
• W2948652296 startingPage "5317" @default.
• W2948652296 abstract "Transition-metal-centered monocyclic boron wheel clusters (M©B nq) represent a family of interesting borometallic compounds with double aromaticity. A variety of early and late transition metal atoms have been found to form such structures with high symmetries and various B n ring sizes. Here we report a combined photoelectron spectroscopy and quantum-chemistry theoretical study of two M©B n- clusters from the middle of the transition metal series: Re©B8- and Re©B9-. Global minimum structure searches revealed that ReB8- adopts a pseudo- C8 v structure while ReB9- is a perfectly planar D9 h molecular wheel. Chemical bonding analyses showed that both clusters exhibit σ and π double aromaticity and obey the electronic design principle for metal-centered borometallic molecular wheels. The central Re atoms are found to possess unusually low oxidation states of +I in Re©B8- and +II in Re©B9-, i.e., the Re atom behaves similarly to late transition metal elements (Ru, Fe, Co, Rh, Ir) in the M©B n- molecular wheels. These two clusters become new members of the family of transition-metal-centered monocyclic borometallic molecular wheels, which may be viable for chemical syntheses with appropriate ligands." @default.
• W2948652296 created "2019-06-14" @default.
• W2948652296 creator A5000053269 @default.
• W2948652296 creator A5020721427 @default.
• W2948652296 creator A5048822014 @default.
• W2948652296 creator A5054159069 @default.
• W2948652296 creator A5059858234 @default.
• W2948652296 creator A5061865238 @default.
• W2948652296 creator A5062786033 @default.
• W2948652296 date "2019-06-03" @default.
• W2948652296 modified "2023-10-16" @default.
• W2948652296 title "Re©B₈^– and Re©B₉^–: New Members of the Transition-Metal-Centered Borometallic Molecular Wheel Family" @default.
• W2948652296 cites W1669798111 @default.
• W2948652296 cites W194243151 @default.
• W2948652296 cites W1975521355 @default.
• W2948652296 cites W1978956583 @default.
• W2948652296 cites W1981368803 @default.
• W2948652296 cites W1982588630 @default.
• W2948652296 cites W1988091937 @default.
• W2948652296 cites W1991853550 @default.
• W2948652296 cites W2004211694 @default.
• W2948652296 cites W2008423326 @default.
• W2948652296 cites W2013180138 @default.
• W2948652296 cites W2015723183 @default.
• W2948652296 cites W2041102233 @default.
• W2948652296 cites W2046679184 @default.
• W2948652296 cites W2060981520 @default.
• W2948652296 cites W2062739549 @default.
• W2948652296 cites W2062991523 @default.
• W2948652296 cites W2065575498 @default.
• W2948652296 cites W2068049269 @default.
• W2948652296 cites W2069006374 @default.
• W2948652296 cites W2074954033 @default.
• W2948652296 cites W2078710135 @default.
• W2948652296 cites W2080897000 @default.
• W2948652296 cites W2083127165 @default.
• W2948652296 cites W2086201379 @default.
• W2948652296 cites W2087864238 @default.
• W2948652296 cites W2095374362 @default.
• W2948652296 cites W2106568431 @default.
• W2948652296 cites W2116373706 @default.
• W2948652296 cites W2125985071 @default.
• W2948652296 cites W2130855680 @default.
• W2948652296 cites W2133927870 @default.
• W2948652296 cites W2138609803 @default.
• W2948652296 cites W2140976435 @default.
• W2948652296 cites W2142764371 @default.
• W2948652296 cites W2163138151 @default.
• W2948652296 cites W2167378797 @default.
• W2948652296 cites W2271355909 @default.
• W2948652296 cites W2293184558 @default.
• W2948652296 cites W2314881547 @default.
• W2948652296 cites W2321910241 @default.
• W2948652296 cites W2326429275 @default.
• W2948652296 cites W2327027767 @default.
• W2948652296 cites W2330060915 @default.
• W2948652296 cites W2336768356 @default.
• W2948652296 cites W2341910381 @default.
• W2948652296 cites W2511938055 @default.
• W2948652296 cites W2551548826 @default.
• W2948652296 cites W2563899968 @default.
• W2948652296 cites W2566651616 @default.
• W2948652296 cites W2567342479 @default.
• W2948652296 cites W2587383645 @default.
• W2948652296 cites W2611008727 @default.
• W2948652296 cites W2741720794 @default.
• W2948652296 cites W2744201848 @default.
• W2948652296 cites W2744997877 @default.
• W2948652296 cites W2760599197 @default.
• W2948652296 cites W2770332248 @default.
• W2948652296 cites W2771919625 @default.
• W2948652296 cites W2826585455 @default.
• W2948652296 cites W2886577591 @default.
• W2948652296 cites W2904221194 @default.
• W2948652296 cites W2904692660 @default.
• W2948652296 cites W2904723664 @default.
• W2948652296 cites W2909539490 @default.
• W2948652296 cites W2916000976 @default.
• W2948652296 cites W2944284653 @default.
• W2948652296 cites W2946009973 @default.
• W2948652296 cites W2951307448 @default.
• W2948652296 doi "https://doi.org/10.1021/acs.jpca.9b03942" @default.
• W2948652296 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31204479" @default.
• W2948652296 hasPublicationYear "2019" @default.
• W2948652296 type Work @default.
• W2948652296 sameAs 2948652296 @default.
• W2948652296 citedByCount "37" @default.
• W2948652296 countsByYear W29486522962019 @default.
• W2948652296 countsByYear W29486522962020 @default.
• W2948652296 countsByYear W29486522962021 @default.
• W2948652296 countsByYear W29486522962022 @default.
• W2948652296 countsByYear W29486522962023 @default.
• W2948652296 crossrefType "journal-article" @default.
• W2948652296 hasAuthorship W2948652296A5000053269 @default.
• W2948652296 hasAuthorship W2948652296A5020721427 @default.
• W2948652296 hasAuthorship W2948652296A5048822014 @default.
• W2948652296 hasAuthorship W2948652296A5054159069 @default.
• W2948652296 hasAuthorship W2948652296A5059858234 @default.

• next