Matches in SemOpenAlex for { <https://semopenalex.org/work/W2948875664> ?p ?o ?g. }
- W2948875664 endingPage "10245" @default.
- W2948875664 startingPage "10239" @default.
- W2948875664 abstract "Abstract A synthetic method to prepare tetrahydroquinoline‐4‐carboxylic acid esters has been developed through the transition‐metal‐catalyzed intramolecular aromatic C−H functionalization of α‐diazoesters. Both [{Pd(IMes)(NQ)} 2 ] (IMes=1,3‐dimesitylimidazol‐2‐ylidene, NQ=1,4‐naphthoquinone) and the first‐generation Grubbs catalyst proved effective for this purpose. The ruthenium catalyst was found to be the most versatile, although in a few cases the palladium complex afforded better yields or selectivities. According to DFT calculations, Pd 0 ‐ and Ru II ‐catalyzed sp 2 ‐C Ar −H functionalization proceeds through different reaction mechanisms. Thus, the Pd 0 ‐catalyzed reaction involves a Pd‐mediated 1,6‐H migration from the sp 2 ‐C Ar −H bond to the carbene carbon atom, followed by a reductive elimination process. In contrast, electrophilic addition of the ruthenacarbene intermediate to the aromatic ring and subsequent 1,2‐proton migration are operative in the Grubbs catalyst promoted reaction." @default.
- W2948875664 created "2019-06-14" @default.
- W2948875664 creator A5009883474 @default.
- W2948875664 creator A5017132696 @default.
- W2948875664 creator A5017815242 @default.
- W2948875664 creator A5039983607 @default.
- W2948875664 date "2019-07-08" @default.
- W2948875664 modified "2023-10-18" @default.
- W2948875664 title "Palladium‐ and Ruthenium‐Catalyzed Intramolecular Carbene C <sub>Ar</sub> −H Functionalization of γ‐Amino‐α‐diazoesters for the Synthesis of Tetrahydroquinolines" @default.
- W2948875664 cites W1148208603 @default.
- W2948875664 cites W1967641329 @default.
- W2948875664 cites W1972760300 @default.
- W2948875664 cites W1983253103 @default.
- W2948875664 cites W1984232099 @default.
- W2948875664 cites W1988091937 @default.
- W2948875664 cites W1999797546 @default.
- W2948875664 cites W2020061813 @default.
- W2948875664 cites W2023271753 @default.
- W2948875664 cites W2024617434 @default.
- W2948875664 cites W2028935067 @default.
- W2948875664 cites W2038533471 @default.
- W2948875664 cites W2040557992 @default.
- W2948875664 cites W2041792275 @default.
- W2948875664 cites W2041811400 @default.
- W2948875664 cites W2048546997 @default.
- W2948875664 cites W2048581867 @default.
- W2948875664 cites W2056348545 @default.
- W2948875664 cites W2058848030 @default.
- W2948875664 cites W2061374950 @default.
- W2948875664 cites W2070740565 @default.
- W2948875664 cites W2079458939 @default.
- W2948875664 cites W2092157292 @default.
- W2948875664 cites W2095474273 @default.
- W2948875664 cites W2143981217 @default.
- W2948875664 cites W2157318649 @default.
- W2948875664 cites W2171999450 @default.
- W2948875664 cites W2269758806 @default.
- W2948875664 cites W2327551693 @default.
- W2948875664 cites W2336251311 @default.
- W2948875664 cites W2486242862 @default.
- W2948875664 cites W2520813766 @default.
- W2948875664 cites W2590259766 @default.
- W2948875664 cites W2593242985 @default.
- W2948875664 cites W2747878051 @default.
- W2948875664 cites W2801137862 @default.
- W2948875664 cites W2803478019 @default.
- W2948875664 cites W2891182568 @default.
- W2948875664 cites W2904318069 @default.
- W2948875664 cites W2907913575 @default.
- W2948875664 cites W2940159625 @default.
- W2948875664 cites W2950668936 @default.
- W2948875664 cites W2951040505 @default.
- W2948875664 cites W2951482407 @default.
- W2948875664 cites W2953344267 @default.
- W2948875664 cites W4249160435 @default.
- W2948875664 cites W4254604633 @default.
- W2948875664 doi "https://doi.org/10.1002/chem.201902104" @default.
- W2948875664 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31169338" @default.
- W2948875664 hasPublicationYear "2019" @default.
- W2948875664 type Work @default.
- W2948875664 sameAs 2948875664 @default.
- W2948875664 citedByCount "11" @default.
- W2948875664 countsByYear W29488756642019 @default.
- W2948875664 countsByYear W29488756642020 @default.
- W2948875664 countsByYear W29488756642021 @default.
- W2948875664 countsByYear W29488756642022 @default.
- W2948875664 countsByYear W29488756642023 @default.
- W2948875664 crossrefType "journal-article" @default.
- W2948875664 hasAuthorship W2948875664A5009883474 @default.
- W2948875664 hasAuthorship W2948875664A5017132696 @default.
- W2948875664 hasAuthorship W2948875664A5017815242 @default.
- W2948875664 hasAuthorship W2948875664A5039983607 @default.
- W2948875664 hasBestOaLocation W29488756642 @default.
- W2948875664 hasConcept C115537861 @default.
- W2948875664 hasConcept C147789679 @default.
- W2948875664 hasConcept C155647269 @default.
- W2948875664 hasConcept C161790260 @default.
- W2948875664 hasConcept C178790620 @default.
- W2948875664 hasConcept C185592680 @default.
- W2948875664 hasConcept C21951064 @default.
- W2948875664 hasConcept C2777164566 @default.
- W2948875664 hasConcept C2778815869 @default.
- W2948875664 hasConcept C2780311995 @default.
- W2948875664 hasConcept C50027330 @default.
- W2948875664 hasConcept C502130503 @default.
- W2948875664 hasConcept C555196967 @default.
- W2948875664 hasConcept C75079739 @default.
- W2948875664 hasConceptScore W2948875664C115537861 @default.
- W2948875664 hasConceptScore W2948875664C147789679 @default.
- W2948875664 hasConceptScore W2948875664C155647269 @default.
- W2948875664 hasConceptScore W2948875664C161790260 @default.
- W2948875664 hasConceptScore W2948875664C178790620 @default.
- W2948875664 hasConceptScore W2948875664C185592680 @default.
- W2948875664 hasConceptScore W2948875664C21951064 @default.
- W2948875664 hasConceptScore W2948875664C2777164566 @default.
- W2948875664 hasConceptScore W2948875664C2778815869 @default.
- W2948875664 hasConceptScore W2948875664C2780311995 @default.
- W2948875664 hasConceptScore W2948875664C50027330 @default.