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- W2948879653 abstract "Block copolymer nanoparticles have been widely used for advanced materials. However, the stabilization is challenging. Herein, we present a method for convenient yet reliable synthesis of stabilized polyion complex (PIC) nanometer-sized spheres and micrometer-sized ultrathin lamellae and vesicles by taking advantage of the wavelength orthogonality of UV-induced disulfide exchange and visible light-initiated polymerization-induced electrostatic self-assembly (PIESA). Disulfide-containing PIC vesicles are synthesized at scale using this PIESA, undergoing a small sphere-to-larger sphere-to-lamella-to-vesicle transition. As such, surface-neutralized and surface-charged micrometer-sized vesicles can be achieved. UV irradiation of the vesicles (5.0 mg/mL in water) in ambient air induces very fast exchange reaction of locally confined/enriched disulfide motifs, leading to cross-linking, shape transition, and cystamine salt release in 4 min. As such, cross-linked PIC spheres, lamellae, and vesicles can be achieved, in one pot, from one single vesicle precursor. The wavelength orthogonality is evident from disabled PIESA synthesis under UV light and ineffective postpolymerization functionalization under visible light. The cross-linked PIC spheres and micrometer-sized ultrathin lamellae and vesicles show outstanding shape/size stability and high reversibility in the solution-adaptive electrostatic hierarchical self-assembly and disassembly upon adding ethanol into aqueous dispersion and subsequent dialysis." @default.
- W2948879653 created "2019-06-14" @default.
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- W2948879653 date "2019-06-07" @default.
- W2948879653 modified "2023-10-12" @default.
- W2948879653 title "Colloidal Stable PIC Vesicles and Lamellae Enabled by Wavelength-Orthogonal Disulfide Exchange and Polymerization-Induced Electrostatic Self-Assembly" @default.
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- W2948879653 cites W1974439691 @default.
- W2948879653 cites W1983224931 @default.
- W2948879653 cites W1986156969 @default.
- W2948879653 cites W1988346172 @default.
- W2948879653 cites W1998429528 @default.
- W2948879653 cites W2004632724 @default.
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- W2948879653 cites W2023520398 @default.
- W2948879653 cites W2026088235 @default.
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- W2948879653 doi "https://doi.org/10.1021/acs.macromol.9b00571" @default.
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