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• W2949061454 startingPage "4788" @default.
• W2949061454 abstract "Heterologous expression of a unique biosynthetic gene cluster (BGC) comprising a highly reducing polyketide synthase and stand-alone thioesterase genes in Aspergillus oryzae enabled us to isolate a novel 34-membered polyene macrolide, phaeospelide A (1). This is the first isolation of a fungal polyene macrolide and the first demonstration of fungal aliphatic macrolide biosynthetic machinery. In addition, sequence similarity network analysis demonstrated the existence of a large number of BGCs for novel fungal macrolides." @default.
• W2949061454 created "2019-06-27" @default.
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• W2949061454 date "2019-06-10" @default.
• W2949061454 modified "2023-10-14" @default.
• W2949061454 title "The Discovery of Fungal Polyene Macrolides via a Postgenomic Approach Reveals a Polyketide Macrocyclization by <i>trans</i>-Acting Thioesterase in Fungi" @default.
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• W2949061454 doi "https://doi.org/10.1021/acs.orglett.9b01674" @default.
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