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- W2949063512 abstract "The title barbiturates are hydrolysed by pyrimidine ring degradation or by cyclopropane ring opening. The cyclopropane ring decreases the hydrolytic reactivity of the pyrimidine moiety in relation to other spirobarbiturates, owing to conjugation between the cyclopropane ring and the C-4 or C-6 carbonyl group. The kinetics and the products of the alcoholysis of these barbiturates have been investigated. The influence of the cyclopropane moiety on the pKa1 values and 13C n.m.r. spectra has also been discussed." @default.
- W2949063512 created "2019-06-27" @default.
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- W2949063512 date "1987-01-27" @default.
- W2949063512 modified "2023-09-26" @default.
- W2949063512 title "ChemInform Abstract: Hydrolysis of Barbituric Acid Derivatives. Part 6. Hydrolysis of Spirocyclopropane- and Spiro-2′-methylcyclopropane-1′,5-barbituric Acids" @default.
- W2949063512 cites W1968328787 @default.
- W2949063512 doi "https://doi.org/10.1002/chin.198704084" @default.
- W2949063512 hasPublicationYear "1987" @default.
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