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- W2949067145 abstract "Multifunctionalized tetrahydroindan derivatives with four stereocenters were constructed via two sequential Michael reactions between cyclic γ,δ-unsaturated-β-ketoester and nitroalkenes initiated with 0.5−2 mol % of cinchona alkaloid based bifunctional organocatalysts and then with 1 equiv of tetramethylguanidine for cyclization. The desired products could be obtained in high yields (up to 99% yield) with excellent enantioselectivities (95−99% ee) as well as diastereoselectivities (up to >99:1 dr) even on a gram scale." @default.
- W2949067145 created "2019-06-27" @default.
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- W2949067145 date "2011-02-10" @default.
- W2949067145 modified "2023-09-25" @default.
- W2949067145 title "Organocatalytic Sequential Michael Reactions: Stereoselective Synthesis of Multifunctionalized Tetrahydroindan Derivatives" @default.
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- W2949067145 doi "https://doi.org/10.1021/ol1029832" @default.
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