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- W2949069608 abstract "Treatment of the 3,4-dioxygenated-9-hydroxy-1-nonyn-5-one derivative, derived from diethyl l-tartrate, with a palladium catalyst in methanol under a CO atmosphere effected an intramolecular acetalization and a stereoselective construction of the (E)-methoxycarbonylmethylidene functionality resulting in formation of the core framework of the diacetylenic spiroacetal enol ether natural products. Chemical transformations of the 1,6-dioxaspiro[4.5]decane derivative thus formed led to the first total synthesis of (−)-AL-2." @default.
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- W2949069608 date "2003-05-30" @default.
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- W2949069608 title "First Total Synthesis of (−)-AL-2" @default.
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- W2949069608 doi "https://doi.org/10.1021/ol0300569" @default.
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