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- W2949070503 abstract "A three-pot synthetic method that features the use of an organocatalyst as the key step was developed for the preparation of biaryl atropisomers. The first reaction is an asymmetric domino Michael-Henry reaction catalyzed by diphenylprolinol silyl ether to afford the substituted nitrocyclohexanecarbaldehyde with four stereogenic centers and one defined configuration of a stereogenic axis with excellent enantioselectivity. Removal of the central chirality from the domino products afforded biaryl atropisomers having axial chirality with excellent enantioselectivity." @default.
- W2949070503 created "2019-06-27" @default.
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- W2949070503 date "2019-07-17" @default.
- W2949070503 modified "2023-09-26" @default.
- W2949070503 title "Asymmetric Synthesis of Biaryl Atropisomers Using an Organocatalyst‐Mediated Domino Reaction as the Key Step" @default.
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- W2949070503 doi "https://doi.org/10.1002/chem.201902767" @default.
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