Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949074747> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2949074747 abstract "C21H26O4, Mr = 342.43, monoclinic, P2(1)/n, a = 7.211 (2), b = 19.521 (6), c = 12.674 (3) A, beta = 95.04 (2) degrees, V = 1777.2 (8) A3, Z = 4, Dx = 1.28 g cm-3, Mo K alpha radiation, lambda = 0.7107 A, mu = 0.8152 cm-1, F(000) = 736, T = 163 K, R = 0.0632 for 3754 reflections [Fo greater than or equal to 4 sigma(Fo)]. The molecules exist as hydrogen-bonded dimers [O14-H14...O16 (related by -x, 1-y, 1-z), O14...O16 2.775 (2), H14...O16 1.93 (2) A, O14-H14...O16 175 (2) degrees] which stack in columns along b. Distortion at the bridgehead double bond is observed. Deviations from ideal values for the torsion angles around the double bond, C7-C8, are as large as 17.8 (2) degrees. The dihedral angle between planes through C6-C7-C8-C11 and C7-C8-C9-C15, the planar portions of the alkene moiety, is 13.4 (9) degrees. The Csp2--Csp3 bond lengths involving C7 are asymmetric with C7-C6 1.501 (2) and C7-C11 1.538 (2) A. The bond length C7-C8 is elongated [1.352 (3) A] for a C-C double bond. The enone system is also non-planar [max. deviation -0.404 (2) A for C10]." @default.
- W2949074747 created "2019-06-27" @default.
- W2949074747 creator A5054440491 @default.
- W2949074747 creator A5055989647 @default.
- W2949074747 creator A5057559974 @default.
- W2949074747 creator A5079868859 @default.
- W2949074747 date "1990-10-30" @default.
- W2949074747 modified "2023-09-24" @default.
- W2949074747 title "ChemInform Abstract: Structure of (.+-.)-(1S*,3S*)-3-Hydroxy-8,11,11-trimethyl-9-oxobicyclo(5.3.1)undec-7-en-1-yl Benzoate" @default.
- W2949074747 cites W2040914008 @default.
- W2949074747 doi "https://doi.org/10.1002/chin.199044265" @default.
- W2949074747 hasPublicationYear "1990" @default.
- W2949074747 type Work @default.
- W2949074747 sameAs 2949074747 @default.
- W2949074747 citedByCount "0" @default.
- W2949074747 crossrefType "journal-article" @default.
- W2949074747 hasAuthorship W2949074747A5054440491 @default.
- W2949074747 hasAuthorship W2949074747A5055989647 @default.
- W2949074747 hasAuthorship W2949074747A5057559974 @default.
- W2949074747 hasAuthorship W2949074747A5079868859 @default.
- W2949074747 hasConcept C112887158 @default.
- W2949074747 hasConcept C115624301 @default.
- W2949074747 hasConcept C155860418 @default.
- W2949074747 hasConcept C178790620 @default.
- W2949074747 hasConcept C185592680 @default.
- W2949074747 hasConcept C188027245 @default.
- W2949074747 hasConcept C193547582 @default.
- W2949074747 hasConcept C32909587 @default.
- W2949074747 hasConcept C61276311 @default.
- W2949074747 hasConcept C68381374 @default.
- W2949074747 hasConcept C71240020 @default.
- W2949074747 hasConcept C8010536 @default.
- W2949074747 hasConcept C89025888 @default.
- W2949074747 hasConceptScore W2949074747C112887158 @default.
- W2949074747 hasConceptScore W2949074747C115624301 @default.
- W2949074747 hasConceptScore W2949074747C155860418 @default.
- W2949074747 hasConceptScore W2949074747C178790620 @default.
- W2949074747 hasConceptScore W2949074747C185592680 @default.
- W2949074747 hasConceptScore W2949074747C188027245 @default.
- W2949074747 hasConceptScore W2949074747C193547582 @default.
- W2949074747 hasConceptScore W2949074747C32909587 @default.
- W2949074747 hasConceptScore W2949074747C61276311 @default.
- W2949074747 hasConceptScore W2949074747C68381374 @default.
- W2949074747 hasConceptScore W2949074747C71240020 @default.
- W2949074747 hasConceptScore W2949074747C8010536 @default.
- W2949074747 hasConceptScore W2949074747C89025888 @default.
- W2949074747 hasLocation W29490747471 @default.
- W2949074747 hasOpenAccess W2949074747 @default.
- W2949074747 hasPrimaryLocation W29490747471 @default.
- W2949074747 hasRelatedWork W1989245064 @default.
- W2949074747 hasRelatedWork W1996260491 @default.
- W2949074747 hasRelatedWork W2017135548 @default.
- W2949074747 hasRelatedWork W2018900068 @default.
- W2949074747 hasRelatedWork W2031266951 @default.
- W2949074747 hasRelatedWork W2034847663 @default.
- W2949074747 hasRelatedWork W2066189369 @default.
- W2949074747 hasRelatedWork W2079839038 @default.
- W2949074747 hasRelatedWork W2080460865 @default.
- W2949074747 hasRelatedWork W2082003882 @default.
- W2949074747 hasRelatedWork W2162203052 @default.
- W2949074747 hasRelatedWork W2949246185 @default.
- W2949074747 hasRelatedWork W2949496203 @default.
- W2949074747 hasRelatedWork W2950437289 @default.
- W2949074747 hasRelatedWork W2950722533 @default.
- W2949074747 hasRelatedWork W2951530893 @default.
- W2949074747 hasRelatedWork W2952816204 @default.
- W2949074747 hasRelatedWork W2953003691 @default.
- W2949074747 hasRelatedWork W2953325807 @default.
- W2949074747 hasRelatedWork W2739940400 @default.
- W2949074747 isParatext "false" @default.
- W2949074747 isRetracted "false" @default.
- W2949074747 magId "2949074747" @default.
- W2949074747 workType "article" @default.