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- W2949083595 abstract "Crystalline Tl2B9H9C2Me2 (1) is obtained in the reaction of the carborane B9H11C2Me2 with two equivalents of thallium(I) ethanolate. An X-ray diffraction study of 1 shows - contrary to the expectation - the presence of isolated thallium ions and thalladicarbollide counteranions. The latter represent ion pairs composed of Tl(I)+ and B9H9C2Me2 inverted left perpendicular 2- units forming slipped icosahedrons. All possible Tl-Tl distances in 1 are too long for even weak attractive interactions, with one exception: A set of symmetry-equivalent cations possesses a Tl-Tl distance of 3.67 angstrom, which is in a range postulated by calculations for weak bonding." @default.
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- W2949083595 date "1991-01-01" @default.
- W2949083595 modified "2023-09-26" @default.
- W2949083595 title "CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS" @default.
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