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- W2949111303 abstract "Catalysed by the nitrile hydratase/amidase-containing Rhodococcus sp. AJ270 cells, a number of β-aryl- and β-alkyl- β-hydroxy-α-methylenepropiononitriles (the Baylis–Hillman nitriles)1 underwent hydrolysis under mild conditions to produce the corresponding enantiomerically enriched Baylis–Hillman amides 2 and acids 3. The enantioselectivity of the biotransformations was strongly determined by the steric effect of the substituents at the β-position of the substrates. The protection of the free hydroxy of β-phenyl-β-hydroxy-α-methylenepropiononitrile 1a by methylation led to the enhancement of enantiocontrol of the biohydrolysis." @default.
- W2949111303 created "2019-06-27" @default.
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- W2949111303 date "2003-07-08" @default.
- W2949111303 modified "2023-09-23" @default.
- W2949111303 title "Nitrile Biotransformations for the Synthesis of Enantiomerically Enriched Baylis—Hillman Adducts." @default.
- W2949111303 cites W2317935645 @default.
- W2949111303 doi "https://doi.org/10.1002/chin.200327027" @default.
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