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- W2949113478 abstract "Abstract Iodine was found to be an efficient catalyst for the aziridination of alkenes utilizing Chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide) as a nitrogen source. For example, when two equivalents of styrene were added to Chloramine-T in the presence of a catalytic amount of iodine in a 1 : 1 solvent mixture of acetonitrile and neutral buffer, the corresponding aziridine 1 was obtained in 91% yield. The reaction could be applied to other acyclic and cyclic alkenes such as 1-octene and cyclohexene. The aziridination of p-substituted styrene derivatives 2–5 with Chloramine-T showed that electron-rich alkenes reacted faster than electron-poor ones. Several Chloramine-T analogs were also examined and were found to give the corresponding aziridines 8–10 in only moderate yields." @default.
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- W2949113478 date "2010-06-17" @default.
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- W2949113478 title "ChemInform Abstract: Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source." @default.
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- W2949113478 doi "https://doi.org/10.1002/chin.199909118" @default.
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