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- W2949124570 abstract "2-Functionalized furans are very easily synthesized by exploiting the dual nucleophilic character of 1,2-dicarbonyls and the dual electrophilic properties of (2-chloro-2-nitroethenyl)benzenes in a one-pot, formal [3+2] cycloaddition. Using a base (DBU), the desired trisubstituted heterocycles were formed rapidly (10–30 min) in good to excellent yields (51–92 %), and this versatile, metal-free methodology was applied to the synthesis of 2-acyl- and 2-carboalkoxyfurans and furan-2-carboxamides. Additionally, by using 2-ketophosphonate derivatives as dinucleophiles, the corresponding 2-phosphorylfurans were formed in good yields (53–74 %)." @default.
- W2949124570 created "2019-06-27" @default.
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- W2949124570 date "2013-03-18" @default.
- W2949124570 modified "2023-09-27" @default.
- W2949124570 title "ChemInform Abstract: Expeditious, Metal-Free, Domino, Regioselective Synthesis of Highly Substituted 2-Carbonyl- and 2-Phosphorylfurans by Formal [3 + 2] Cycloaddition." @default.
- W2949124570 cites W2113538988 @default.
- W2949124570 doi "https://doi.org/10.1002/chin.201313082" @default.
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