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- W2949130179 abstract "Alkylideneaminyl radicals are generated from O-2,4-dinitrophenyloximes of γ,δ-unsaturated ketones by treatment with NaH and 3,4-methylenedioxyphenol. The resulting radical species successively add to the olefinic moiety intramolecularly to afford dihydropyrroles in the presence of a radical trapping agent. This method is applied for the stereoselective synthesis of xenovenine, a bicyclic 3,5-dialkylpyrrolizidine alkaloid." @default.
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- W2949130179 date "1999-07-01" @default.
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- W2949130179 title "Synthesis of dihydropyrroles by the intramolecular addition of alkylideneaminyl radicals generated from O-2,4-dinitrophenyloximes of γ,δ-unsaturated ketones" @default.
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