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- W2949131421 abstract "The gaseous species SiO(OH) and SiO(OH)2 were detected as products of the reaction of SiO2(l) and H2O(g) near 2000 K, using effusion‐beam mass spectrometry. No other silicon‐containing hydroxides or oxyhydroxides were observed. From third law analysis of equilibrium data, values of ΔfH°298 of SiO(OH) and SiO(OH)2 were evaluated as −118 and −213 kcal mol−1, respectively, both ±4 kcal mol−1. Several equilibrium measurements on gaseous SiO2 yielded a ΔfH°298 value of −67 kcal mol−1, which is 6–10 kcal mol−1 less stable than values given in most compilations. It appears that the new thermochemical data for SiO(OH) and SiO(OH)2, plus a literature estimate for Si2O(OH)6, can be used to model the equilibrium behavior of the silica–steam system over a wide range of temperatures and pressures." @default.
- W2949131421 created "2019-06-27" @default.
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- W2949131421 date "2010-08-18" @default.
- W2949131421 modified "2023-09-24" @default.
- W2949131421 title "ChemInform Abstract: Thermochemistry of Gaseous SiO(OH), SiO(OH)2, and SiO2." @default.
- W2949131421 cites W2024212429 @default.
- W2949131421 doi "https://doi.org/10.1002/chin.199504013" @default.
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