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- W2949138770 abstract "The reactions of norbornadiene in amine by the use of nickel, palladium and rhodium complexes have been studied in the presence of protic acid. A catalytic system of Ni(COD)2 (1)-n-Bu3P gives a mixture of 5-exo-(o-tolyl)-2-norbornene (3) and 5-exo-(N-amino)-2-norbornene (4). Bis(triphenylphosphine)(maleic anhydride)palladium (5) gives 3-(N-amino)nortricyclene (6). Dichlorotetrakis(cyclooctene)dirhodium (10) gives a [2+4] cycloaddition product (11). All these reactions mechanisms are discussed from the point of view of an acid-promoted reaction on low-valent transition metal complexes." @default.
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- W2949138770 date "1975-01-07" @default.
- W2949138770 modified "2023-09-23" @default.
- W2949138770 title "ChemInform Abstract: THE AMINATION AND DIMERIZATION OF NORBORNADIENE WITH NICKEL, PALLADIUM, AND RHODIUM COMPLEXES" @default.
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- W2949138770 doi "https://doi.org/10.1002/chin.197501184" @default.
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