FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949144947> ?p ?o ?g. }

• W2949144947 endingPage "1233" @default.
• W2949144947 startingPage "1226" @default.
• W2949144947 abstract "The binary systems Ca-Sn, Ba-Sn, Eu-Sn, Yb-Sn, Sr-Pb, Ba-Pb, and Eu-Pb do not contain Cr(5)B(3)-like A(5)Tt(3) phases when care is taken to exclude hydrogen from the reactions (Tt = tetrel, Si-Pb). All form ternary A(5)Tt(3)H(x)() phases (x < or = 1) with stuffed Cr(5)B(3)-like structures instead, and all of those tested, Ca-Sn, Ba-Sn, Sr-Pb, and Ba-Pb, also yield the isostructural A(5)Tt(3)F. The structures and compositions of Ca(5)Sn(3)H(x), Ca(5)Sn(3)F(0.89), Eu(5)Sn(3)H(x), and Sr(5)Pb(3)F have been refined from single-crystal X-ray diffraction data and of Ca(5)Sn(3)D from powder neutron data. The interstitial H, F atoms are bound in a tetrahedral (A(2+))(4) cavity in a Cr(5)B(3)-type metal atom structure. Nine previous reports of binary Ba(5)Sn(3), Yb(5)Sn(3), Sr(5)Pb(3), and Ba(5)Pb(3) compounds were wrong and presumably concerned the hydrides. The new ternary phases are generally Pauli-paramagnetic, evidently with pi electrons from the characteristic tetrelide dimers in this structure type at least partially delocalized into the conduction band. The Sn-Sn bonds appear correspondingly shortened on oxidation. Other new phases reported are CaSn (CrB type), Yb(5)Sn(4)H(x) (Sm(5)Ge(4)), YbSn ( approximately TlTe), Ba(5)Pb(3) ( approximately W(5)Si(3)), and Yb(31)Pb(20) (Ca(31)Sn(20))." @default.
• W2949144947 created "2019-06-27" @default.
• W2949144947 creator A5071854978 @default.
• W2949144947 creator A5077317664 @default.
• W2949144947 date "2001-02-06" @default.
• W2949144947 modified "2023-10-17" @default.
• W2949144947 title "Hydrogen Impurity Effects. A₅Tt₃Z Intermetallic Compounds between A = Ca, Sr, Ba, Eu, Yb and Tt = Sn, Pb with Cr₅B₃-like Structures That Are Stabilized by Hydride or Fluoride (Z)" @default.
• W2949144947 cites W172353037 @default.
• W2949144947 cites W1744894025 @default.
• W2949144947 cites W1963964399 @default.
• W2949144947 cites W1967556257 @default.
• W2949144947 cites W1978081239 @default.
• W2949144947 cites W1982718477 @default.
• W2949144947 cites W2044616859 @default.
• W2949144947 cites W2055840191 @default.
• W2949144947 cites W2056241297 @default.
• W2949144947 cites W2060421271 @default.
• W2949144947 cites W2063274820 @default.
• W2949144947 cites W2067618428 @default.
• W2949144947 cites W2070274453 @default.
• W2949144947 cites W2070573346 @default.
• W2949144947 cites W2074378291 @default.
• W2949144947 cites W2074826222 @default.
• W2949144947 cites W2075659417 @default.
• W2949144947 cites W2083715826 @default.
• W2949144947 cites W2089969800 @default.
• W2949144947 cites W2090120961 @default.
• W2949144947 cites W2103307091 @default.
• W2949144947 cites W2167590372 @default.
• W2949144947 cites W287546354 @default.
• W2949144947 cites W2950773035 @default.
• W2949144947 cites W2951695281 @default.
• W2949144947 cites W2952194166 @default.
• W2949144947 cites W2952210125 @default.
• W2949144947 cites W2952919735 @default.
• W2949144947 cites W4234967463 @default.
• W2949144947 doi "https://doi.org/10.1021/ic0010306" @default.
• W2949144947 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11300823" @default.
• W2949144947 hasPublicationYear "2001" @default.
• W2949144947 type Work @default.
• W2949144947 sameAs 2949144947 @default.
• W2949144947 citedByCount "37" @default.
• W2949144947 countsByYear W29491449472012 @default.
• W2949144947 countsByYear W29491449472015 @default.
• W2949144947 countsByYear W29491449472018 @default.
• W2949144947 countsByYear W29491449472020 @default.
• W2949144947 countsByYear W29491449472021 @default.
• W2949144947 crossrefType "journal-article" @default.
• W2949144947 hasAuthorship W2949144947A5071854978 @default.
• W2949144947 hasAuthorship W2949144947A5077317664 @default.
• W2949144947 hasConcept C115624301 @default.
• W2949144947 hasConcept C178790620 @default.
• W2949144947 hasConcept C185592680 @default.
• W2949144947 hasConcept C199360897 @default.
• W2949144947 hasConcept C205188671 @default.
• W2949144947 hasConcept C27501479 @default.
• W2949144947 hasConcept C2780026712 @default.
• W2949144947 hasConcept C41008148 @default.
• W2949144947 hasConcept C64452783 @default.
• W2949144947 hasConcept C70050531 @default.
• W2949144947 hasConcept C73585123 @default.
• W2949144947 hasConcept C8010536 @default.
• W2949144947 hasConceptScore W2949144947C115624301 @default.
• W2949144947 hasConceptScore W2949144947C178790620 @default.
• W2949144947 hasConceptScore W2949144947C185592680 @default.
• W2949144947 hasConceptScore W2949144947C199360897 @default.
• W2949144947 hasConceptScore W2949144947C205188671 @default.
• W2949144947 hasConceptScore W2949144947C27501479 @default.
• W2949144947 hasConceptScore W2949144947C2780026712 @default.
• W2949144947 hasConceptScore W2949144947C41008148 @default.
• W2949144947 hasConceptScore W2949144947C64452783 @default.
• W2949144947 hasConceptScore W2949144947C70050531 @default.
• W2949144947 hasConceptScore W2949144947C73585123 @default.
• W2949144947 hasConceptScore W2949144947C8010536 @default.
• W2949144947 hasIssue "6" @default.
• W2949144947 hasLocation W29491449471 @default.
• W2949144947 hasLocation W29491449472 @default.
• W2949144947 hasOpenAccess W2949144947 @default.
• W2949144947 hasPrimaryLocation W29491449471 @default.
• W2949144947 hasRelatedWork W1977990765 @default.
• W2949144947 hasRelatedWork W2000773263 @default.
• W2949144947 hasRelatedWork W2023266934 @default.
• W2949144947 hasRelatedWork W2047009609 @default.
• W2949144947 hasRelatedWork W2050775256 @default.
• W2949144947 hasRelatedWork W2059021401 @default.
• W2949144947 hasRelatedWork W2318250919 @default.
• W2949144947 hasRelatedWork W2324801237 @default.
• W2949144947 hasRelatedWork W2950813496 @default.
• W2949144947 hasRelatedWork W2952517343 @default.
• W2949144947 hasVolume "40" @default.
• W2949144947 isParatext "false" @default.
• W2949144947 isRetracted "false" @default.
• W2949144947 magId "2949144947" @default.
• W2949144947 workType "article" @default.