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- W2949161330 abstract "The treatment of (arylcyanomethyl)(cyanomethyl)dimethylammonium salts 3 with base/solvent systems A (25 % aq sodium hydroxide/benzene), B (solid potassium carbonate/dimethylformamide or C (25 % aq ammonia/dichloromethane) generated ylides which undergo [3,2] and/or a new [1,4] sigmatropic rearrangement to give ortho-cyanomethyl-substituted 2-dimethylamino-2-phenylacetonitriles 5 and/or 6. The unmasking of the carbonyl group in these products gave ortho-cyanomethyl-substituted aromatic aldehydes 7 and/or 8, respectively." @default.
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- W2949161330 date "1991-01-01" @default.
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- W2949161330 title "New [1,4] Sigmatropic Rearrangement of Ammonium Benzylides: Synthesis of<i>ortho</i>-Cyanomethyl-Substituted Aromatic Aldehydes" @default.
- W2949161330 doi "https://doi.org/10.1055/s-1991-20774" @default.
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