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- W2949161738 startingPage "925" @default.
- W2949161738 abstract "Expanded porphyrins and their metal complexes have shown considerable potentials in medicinal applications such as diagnostic or treatment tools for various deseases. The hybrid macrocycles composed of the combination of part of the porphyrin and part of the Schiff-base have shown interesting physico-chemical properties. Since the report of the synthesis of fully aromatic expanded porphyrins and their metal complexes by Sessler et al., many new macroaromatic porphyrinoids consisted with tripyrromethanes and imines have been synthesized and studied for potential biological applications. For example, some of the lanthanide complexes of the expanded porphyrins have been used for enhancing images in MRI or for selective anion binding agents. The unusual contractive cyclization accompanying with C-C bond cleavage was reported in some condensation reactions. Here, we extend the reactions further and report the identification and solid state structure of the synthesized macrocycles. Results and Discussions" @default.
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- W2949161738 date "2006-06-20" @default.
- W2949161738 modified "2023-09-24" @default.
- W2949161738 title "Synthesis and Structure of Non-aromatic Porphyrinoid Schiff-base Macrocycles Bearing Thiophene" @default.
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- W2949161738 doi "https://doi.org/10.5012/bkcs.2006.27.6.925" @default.
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