Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949174961> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2949174961 abstract "Abstract Starting from (2 R ,5 R )-2,5-bis(methoxymethyl)pyrrolidine 1 , hydroxylamine cis - 3 was synthesized with high stereoselectivity by successive oxidation and addition of PhMgBr. By using PhLi, trans ( C 2 -chiral) pyrrolidine nitroxide trans - 7 was obtained from nitrone 5 derived from hydroxylamine 3 . The cis ( meso ) counterpart cis - 7 was produced along with trans - 7 when PhMgBr was employed in place of PhLi. Moreover, cis - 7 was also obtained selectively by using PhLi and Et 2 AlCl with nitrone 5 . The change of stereochemical bias observed when EtMgBr and/or nitrone 10 bearing an ethyl group were employed is also discussed." @default.
- W2949174961 created "2019-06-27" @default.
- W2949174961 creator A5067304768 @default.
- W2949174961 creator A5072470765 @default.
- W2949174961 creator A5079009410 @default.
- W2949174961 date "2000-10-10" @default.
- W2949174961 modified "2023-09-27" @default.
- W2949174961 title "ChemInform Abstract: Highly Stereoselective Synthesis of C2-Chiral and meso Nitroxides from an Optically Active Pyrrolidine" @default.
- W2949174961 cites W1977874279 @default.
- W2949174961 doi "https://doi.org/10.1002/chin.200041093" @default.
- W2949174961 hasPublicationYear "2000" @default.
- W2949174961 type Work @default.
- W2949174961 sameAs 2949174961 @default.
- W2949174961 citedByCount "0" @default.
- W2949174961 crossrefType "journal-article" @default.
- W2949174961 hasAuthorship W2949174961A5067304768 @default.
- W2949174961 hasAuthorship W2949174961A5072470765 @default.
- W2949174961 hasAuthorship W2949174961A5079009410 @default.
- W2949174961 hasConcept C111998727 @default.
- W2949174961 hasConcept C161790260 @default.
- W2949174961 hasConcept C166940927 @default.
- W2949174961 hasConcept C169912494 @default.
- W2949174961 hasConcept C178790620 @default.
- W2949174961 hasConcept C181647583 @default.
- W2949174961 hasConcept C185592680 @default.
- W2949174961 hasConcept C2775999725 @default.
- W2949174961 hasConcept C2778851528 @default.
- W2949174961 hasConcept C2779440280 @default.
- W2949174961 hasConcept C2779664164 @default.
- W2949174961 hasConcept C3019471444 @default.
- W2949174961 hasConcept C521977710 @default.
- W2949174961 hasConcept C71240020 @default.
- W2949174961 hasConceptScore W2949174961C111998727 @default.
- W2949174961 hasConceptScore W2949174961C161790260 @default.
- W2949174961 hasConceptScore W2949174961C166940927 @default.
- W2949174961 hasConceptScore W2949174961C169912494 @default.
- W2949174961 hasConceptScore W2949174961C178790620 @default.
- W2949174961 hasConceptScore W2949174961C181647583 @default.
- W2949174961 hasConceptScore W2949174961C185592680 @default.
- W2949174961 hasConceptScore W2949174961C2775999725 @default.
- W2949174961 hasConceptScore W2949174961C2778851528 @default.
- W2949174961 hasConceptScore W2949174961C2779440280 @default.
- W2949174961 hasConceptScore W2949174961C2779664164 @default.
- W2949174961 hasConceptScore W2949174961C3019471444 @default.
- W2949174961 hasConceptScore W2949174961C521977710 @default.
- W2949174961 hasConceptScore W2949174961C71240020 @default.
- W2949174961 hasLocation W29491749611 @default.
- W2949174961 hasOpenAccess W2949174961 @default.
- W2949174961 hasPrimaryLocation W29491749611 @default.
- W2949174961 hasRelatedWork W1977874279 @default.
- W2949174961 hasRelatedWork W1986334017 @default.
- W2949174961 hasRelatedWork W2005349621 @default.
- W2949174961 hasRelatedWork W2018028685 @default.
- W2949174961 hasRelatedWork W2020619946 @default.
- W2949174961 hasRelatedWork W2040355838 @default.
- W2949174961 hasRelatedWork W2042488484 @default.
- W2949174961 hasRelatedWork W2047494333 @default.
- W2949174961 hasRelatedWork W2071235409 @default.
- W2949174961 hasRelatedWork W2086917971 @default.
- W2949174961 hasRelatedWork W2159710785 @default.
- W2949174961 hasRelatedWork W2161626899 @default.
- W2949174961 hasRelatedWork W2949106114 @default.
- W2949174961 hasRelatedWork W2950772221 @default.
- W2949174961 hasRelatedWork W2951606873 @default.
- W2949174961 hasRelatedWork W2951692519 @default.
- W2949174961 hasRelatedWork W2951882287 @default.
- W2949174961 hasRelatedWork W2952140433 @default.
- W2949174961 hasRelatedWork W2952950125 @default.
- W2949174961 hasRelatedWork W2953046830 @default.
- W2949174961 isParatext "false" @default.
- W2949174961 isRetracted "false" @default.
- W2949174961 magId "2949174961" @default.
- W2949174961 workType "article" @default.