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- W2949179984 abstract "Chiral β-amidophosphine boranes 7a−f can be diastereoselectively alkylated, using O-protected amino-alcohols as chiral inducers, to furnish α-substituted β-amidophosphine boranes 8a−f and 9−12 with up to 72% diastereoisomeric excess. Selective deprotection afforded optically pure carboxylic derivative 13 which is a key intermediate for the synthesis of various potential chiral ligands for asymmetric catalysis." @default.
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- W2949179984 date "2001-07-19" @default.
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- W2949179984 title "Synthesis of α-Substituted β-Amidophosphines by Diastereoselective Alkylation. A New Access to Chiral Ligands for Asymmetric Catalysis" @default.
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- W2949179984 doi "https://doi.org/10.1021/jo0155759" @default.
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