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- W2949181505 abstract "Palladium-catalyzed allylic substitution reactions are among the most efficient methods to construct C-C bonds between sp(3)-hybridized carbon atoms. In contrast, much less work has been done with nickel catalysts, perhaps because of the different mechanisms of the allylic substitution reactions. Palladium catalysts generally undergo substitution by a pathway, wherein the nucleophile attacks the allyl group externally. Nickel catalysts are usually paired with hard nucleophiles, which attack the metal before C-C bond formation. Introduced herein is a rare nickel-based catalyst which promotes substitution with diarylmethane pronucleophiles by the soft-nucleophile pathway. Preliminary studies on the asymmetric allylic alkylation are promising." @default.
- W2949181505 created "2019-06-27" @default.
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- W2949181505 date "2016-05-01" @default.
- W2949181505 modified "2023-09-27" @default.
- W2949181505 title "ChemInform Abstract: Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights." @default.
- W2949181505 cites W2267483994 @default.
- W2949181505 doi "https://doi.org/10.1002/chin.201621069" @default.
- W2949181505 hasPublicationYear "2016" @default.
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