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- W2949199899 abstract "Abstract Reaction of 2-alkenyl-1,3,2-benzodioxaboroles, which are readily accessible by hydroboration of alkynes with catecholborane, with α,β-unsaturated ketones in the presence of rhodium (S)- binap catalyst and triethylamine in dioxane H 2 O ( 10 1 ) proceeded with high enantioselectivity at 100 °C to give high yields of optically active β-alkenyl ketones of over 90% ee. One pot synthesis of the 1,4-addition product is also successful in the rhodium-catalyzed asymmetric reaction by use of alkenylboranes generated in situ from alkyne and catecholborane." @default.
- W2949199899 created "2019-06-27" @default.
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- W2949199899 date "2010-06-17" @default.
- W2949199899 modified "2023-09-24" @default.
- W2949199899 title "ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of 2-Alkenyl-1,3,2-benzodioxaboroles to α,β-Unsaturated Ketones." @default.
- W2949199899 cites W2060146629 @default.
- W2949199899 doi "https://doi.org/10.1002/chin.199906033" @default.
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