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- W2949202880 abstract "Infrared spectra of acrylyl fluoride have been studied in the vapor phase and in neon, argon, and nitrogen matrices in the regions 200–4000 cm−1 and all fundamental vibrations have been assigned for the s‐cis and s‐trans rotamers. Isomerization frequency shifts of 19, 20, and 41 cm−1 are found for certain–OCF modes, though most vibrations show much smaller shifts. Many vapor phase band contours are complex due to the overlap of several modes; the matrix‐isolation experiments clarify this data and in some instances provide intense fundamentals that are not detected in conventional sampling. The matrix isolation of large populations of both s‐cis and s‐trans rotamers suggests that there is a small potential energy difference between these two forms but that a large potential barrier hinders their interconversion. The results are consistent with the magnetic resonance study of Lin and Servis [J. Am. Chem. Soc. 94, 5794 (1972)] and their two data points, together with s‐cis and s‐trans C–C torsion frequencies..." @default.
- W2949202880 created "2019-06-27" @default.
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- W2949202880 date "1975-09-09" @default.
- W2949202880 modified "2023-09-25" @default.
- W2949202880 title "ChemInform Abstract: INFRARED MATRIX-ISOLATION SPECTRA OF ACRYLYL FLUORIDE ROTAMERS" @default.
- W2949202880 cites W2055467673 @default.
- W2949202880 doi "https://doi.org/10.1002/chin.197536053" @default.
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