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- W2949202942 abstract "Abstract Anodic regioselective fluorination of α -phenylsulphenylated ethyl acetates and acetonitriles of 1-naphthalene and 2-pyridine derivatives was investigated. 1-Naphthalene derivatives were selectively fluorinated at the α -carbon using Et 3 N·3HF/CH 3 CN in high yields while those devoid of an α -phenylsulphenyl group gave non-regioselectively polyfluorinated products. On the contrary, α -phenylsulphenylated 2-pyridine derivatives gave the corresponding α -fluoro compounds in low yields in CH 3 CN. The fluorinated products were obtained in much better-yields in DME. Moreover, their yields were significantly improved by the addition of Ph 2 S." @default.
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- W2949202942 date "2010-06-20" @default.
- W2949202942 modified "2023-09-23" @default.
- W2949202942 title "ChemInform Abstract: Electrolytic Partial Fluorination of Organic Compounds. Part 25. Regioselective Anodic Fluorination of Naphthalene- and Pyridine-acetate and -acetonitrile Derivatives." @default.
- W2949202942 cites W2003678579 @default.
- W2949202942 doi "https://doi.org/10.1002/chin.199829061" @default.
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