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- W2949203964 abstract "A cell-free extract from the calli of the liverwortHeteroscyphus planus catalyzes the divalent metal ion-dependentconversion of (2Z, 6E)-farnesyl diphosphate (FPP) into(-)-γ-cadinene and (+)-germacreneD, while it specifically converts (2E, 6E)-FPP into(+)-cubenene and (+)-epicubenol. The 1,3-hydride shiftin the formation of (-)-γ-cadinene has beendetermined by conversion of (2Z,6E)-[1,1-2H2]-FPP into(-)-γ-cadinene which was shown byGLC–MS and 2H NMR spectroscopy to be labelled at theC-11 position. These findings suggest that(-)-γ-cadinene is directly formed from2Z, 6E-FPP by intramolecular electrophilic attack ofthe primary carbocation on the C-10 position of FPP.(+)-Cubenene synthase and (-)-γ-cadinene synthase has beenpurified by fractionation with ammonium sulfate, gel filtration onSephacryl S-200 HR and anion exchange chromatography on DEAE-SepharoseCL-6B. Separation of (-)-γ-cadinene synthase from(+)-cubenene synthase is facilitated by a change in the elutionbehaviour of enzymes during anion exchange chromatography. All theevidence strongly suggests that the activities of (+)-cubenenesynthase and (+)-epicubenol synthase are dual functions of thesame enzyme." @default.
- W2949203964 created "2019-06-27" @default.
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- W2949203964 date "2010-08-02" @default.
- W2949203964 modified "2023-09-27" @default.
- W2949203964 title "ChemInform Abstract: In vitro Biosynthesis of Cadinanes by Cell-Free Extracts of Cultured Cells of Heteroscyphus planus." @default.
- W2949203964 cites W2151784217 @default.
- W2949203964 doi "https://doi.org/10.1002/chin.199748228" @default.
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