Matches in SemOpenAlex for { <https://semopenalex.org/work/W2949204622> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2949204622 endingPage "7507" @default.
- W2949204622 startingPage "7501" @default.
- W2949204622 abstract "A facile total synthesis of (+)-hernandulcin (1) was accomplished from (−)-isopulegol in 6 steps with 15% overall yield. Epoxidation of (−)-isopulegol with m-chloroperbenzoic acid followed by opening of the epoxide 3a with prenyl Grignard afforded the tertiary alcohol 4a with correct C-6 and C-1′ stereochemistry as a major product. Oxidation of the secondary alcohol in compound 4a to the ketone 5a was accomplished in high yield by using TPAP and N-methylmorpholine N-oxide. Conversion of the ketone 5a to α,β-unsaturated ketone via organoselenium intermediate gave (+)-hernandulcin (1). This method was also successfully applied to the synthesis of (+)-epihernandulcin (2)." @default.
- W2949204622 created "2019-06-27" @default.
- W2949204622 creator A5058563246 @default.
- W2949204622 creator A5066112203 @default.
- W2949204622 creator A5066372767 @default.
- W2949204622 date "2003-09-01" @default.
- W2949204622 modified "2023-09-24" @default.
- W2949204622 title "A facile synthesis of (6 S ,1′ S )-(+)-hernandulcin and (6 S ,1′ R )-(+)-epihernandulcin" @default.
- W2949204622 cites W1493198325 @default.
- W2949204622 cites W1967159419 @default.
- W2949204622 cites W1973005785 @default.
- W2949204622 cites W1977142794 @default.
- W2949204622 cites W1992071524 @default.
- W2949204622 cites W1994643105 @default.
- W2949204622 cites W1998890862 @default.
- W2949204622 cites W2008153326 @default.
- W2949204622 cites W2017832862 @default.
- W2949204622 cites W2019947616 @default.
- W2949204622 cites W2033660928 @default.
- W2949204622 cites W2033744552 @default.
- W2949204622 cites W2034628779 @default.
- W2949204622 cites W2039469764 @default.
- W2949204622 cites W2052051360 @default.
- W2949204622 cites W2061318222 @default.
- W2949204622 cites W2064912418 @default.
- W2949204622 cites W2071761807 @default.
- W2949204622 cites W2080754199 @default.
- W2949204622 cites W2121127744 @default.
- W2949204622 cites W2177328130 @default.
- W2949204622 cites W2318273868 @default.
- W2949204622 cites W2949131619 @default.
- W2949204622 cites W4240347766 @default.
- W2949204622 doi "https://doi.org/10.1016/s0040-4020(03)01168-2" @default.
- W2949204622 hasPublicationYear "2003" @default.
- W2949204622 type Work @default.
- W2949204622 sameAs 2949204622 @default.
- W2949204622 citedByCount "18" @default.
- W2949204622 countsByYear W29492046222013 @default.
- W2949204622 countsByYear W29492046222015 @default.
- W2949204622 countsByYear W29492046222017 @default.
- W2949204622 countsByYear W29492046222019 @default.
- W2949204622 countsByYear W29492046222020 @default.
- W2949204622 countsByYear W29492046222021 @default.
- W2949204622 crossrefType "journal-article" @default.
- W2949204622 hasAuthorship W2949204622A5058563246 @default.
- W2949204622 hasAuthorship W2949204622A5066112203 @default.
- W2949204622 hasAuthorship W2949204622A5066372767 @default.
- W2949204622 hasConcept C134121241 @default.
- W2949204622 hasConcept C161790260 @default.
- W2949204622 hasConcept C178790620 @default.
- W2949204622 hasConcept C185592680 @default.
- W2949204622 hasConcept C191897082 @default.
- W2949204622 hasConcept C192562407 @default.
- W2949204622 hasConcept C2776920199 @default.
- W2949204622 hasConcept C2777738585 @default.
- W2949204622 hasConcept C2780616238 @default.
- W2949204622 hasConcept C2781066024 @default.
- W2949204622 hasConcept C40875361 @default.
- W2949204622 hasConceptScore W2949204622C134121241 @default.
- W2949204622 hasConceptScore W2949204622C161790260 @default.
- W2949204622 hasConceptScore W2949204622C178790620 @default.
- W2949204622 hasConceptScore W2949204622C185592680 @default.
- W2949204622 hasConceptScore W2949204622C191897082 @default.
- W2949204622 hasConceptScore W2949204622C192562407 @default.
- W2949204622 hasConceptScore W2949204622C2776920199 @default.
- W2949204622 hasConceptScore W2949204622C2777738585 @default.
- W2949204622 hasConceptScore W2949204622C2780616238 @default.
- W2949204622 hasConceptScore W2949204622C2781066024 @default.
- W2949204622 hasConceptScore W2949204622C40875361 @default.
- W2949204622 hasIssue "38" @default.
- W2949204622 hasLocation W29492046221 @default.
- W2949204622 hasOpenAccess W2949204622 @default.
- W2949204622 hasPrimaryLocation W29492046221 @default.
- W2949204622 hasRelatedWork W2000595855 @default.
- W2949204622 hasRelatedWork W2026244148 @default.
- W2949204622 hasRelatedWork W2042523947 @default.
- W2949204622 hasRelatedWork W2047888616 @default.
- W2949204622 hasRelatedWork W2067572013 @default.
- W2949204622 hasRelatedWork W2147427301 @default.
- W2949204622 hasRelatedWork W2326148101 @default.
- W2949204622 hasRelatedWork W2804876437 @default.
- W2949204622 hasRelatedWork W2949204622 @default.
- W2949204622 hasRelatedWork W2949836300 @default.
- W2949204622 hasVolume "59" @default.
- W2949204622 isParatext "false" @default.
- W2949204622 isRetracted "false" @default.
- W2949204622 magId "2949204622" @default.
- W2949204622 workType "article" @default.