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- W2949206961 abstract "Abstract A practical synthetic scheme that incorporates an amide functionality into the rigid framework of (2 S ,3 R )-3-hydroxypipecolic acid to produce novel hydroxylated δ-lactam derivatives is reported. The reaction sequence includes the transformation of chiral furanylazide to a 2 S -hydroxymethyldihydro pyridone, which was reduced diasteroselectively, protected and oxidized to two corresponding δ-lactam derivatives. Asymmetric dihydroxylation and oxidation of the latter compounds afforded two chiral (2 R ,3 S )-3-hydroxypipecolic acid δ-lactam derivatives." @default.
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- W2949206961 date "2002-08-01" @default.
- W2949206961 modified "2023-09-25" @default.
- W2949206961 title "Asymmetric synthesis of (2R,3S)-3-hydroxypipecolic acid δ-lactam derivatives" @default.
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- W2949206961 doi "https://doi.org/10.1016/s0040-4020(02)00674-9" @default.
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