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- W2949207850 abstract "Oxidative transformations of phenols have attracted significant attention of chemists due to their importance in biological process and organic synthesis. In contrast to the relatively well-developed oxygenation and coupling reactions of phenols, the highly efficient and selective oxidative ring cleavage of phenols is under-represented. This work describes a novel CuCl-catalyzed tandem homocoupling/skeletal rearrangement of phenols that realizes the cleavage of the phenol ring by using air or Ag2CO3 as the oxidant. Interestingly, simply changing the oxidant to K2S2O8 results in the oxidative coupling/cyclization of phenols to give dibenzofurans. These results set an important precedent of oxidant-controlled catalytic transformations of phenols." @default.
- W2949207850 created "2019-06-27" @default.
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- W2949207850 date "2016-02-01" @default.
- W2949207850 modified "2023-09-23" @default.
- W2949207850 title "ChemInform Abstract: Oxidant-Controlled Catalytic Transformations of Phenols with Unexpected Cleavage of Aromatic Rings." @default.
- W2949207850 cites W2135261378 @default.
- W2949207850 doi "https://doi.org/10.1002/chin.201608124" @default.
- W2949207850 hasPublicationYear "2016" @default.
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