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• W2949209068 abstract "Three new vanadoborates [Zn 4 V 10 B 34 O 84 H 10 ](H 2 dap) 4 (dap) 2 ·9H 2 O ( 1 ), [Zn(H 2 teta) 2 V 12 B 18 O 54 -(OH) 6 ]·4H 3 O ( 2 ) and [Zn(H 3 tepa)V 12 B 18 O 54 (OH) 6 ][H 2 en] 2 ·H 3 O·3H 2 O ( 3 ) have been hydrothermally synthesized and structurally characterized. 1 consists of new cluster [Zn 4 V 10 B 34 O 84 H 10 ] 8 − with the rare [Zn 4 B 4 O 18 ] unit, protonated H 2 dap 2 + , free dap and H 2 O molecules. Both 2 and 3 contain [V 12 B 18 O 54 (OH) 6 (H 2 O)] 10 − clusters, which are connected by [Zn(H 2 teta) 2 ] 2 + /[Zn(H 3 tepa)] 2 + groups as bridges into 1-D chain. The magnetic susceptibility of 3 shows the antiferromagnetic interaction between V IV cations. The integration of tetrahedral [ZnO 4 ] units into B–O–V cluster framework gives an interesting vanadoborate cluster [Zn 4 V 10 B 34 O 84 H 10 ] 8 − ." @default.
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• W2949209068 date "2014-05-01" @default.
• W2949209068 modified "2023-10-14" @default.
• W2949209068 title "Three new vanadoborates functionalized with zinc complexes" @default.
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• W2949209068 doi "https://doi.org/10.1016/j.inoche.2014.02.024" @default.
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