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- W2949211529 abstract "We have studied the ability of an α-imino glyoxylamide derived from (S,S)-(+)-pseudoephedrine as a valuable chiral electrophile for the preparation of α-amino carbonyl compounds. In this context, the addition of Grignard reagents to the azomethine moiety of this chiral electrophile afforded the expected α-amino amide adducts in good yields and diastereoselectivities. Moreover, these adducts have been transformed into enantioenriched α-amino ketones by exploiting the ability of pseudoephedrine amides to undergo selective monoaddition to the carbamoyl group with organolithium reagents." @default.
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- W2949211529 date "2008-05-20" @default.
- W2949211529 modified "2023-09-23" @default.
- W2949211529 title "(<i>S</i>,<i>S</i>)-(+)-Pseudoephedrine α-Iminoglyoxylamide as a Chiral Glycine Cation Equivalent: A Modular and Flexible Approach to Enantioenriched α-Amino Ketones" @default.
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- W2949211529 doi "https://doi.org/10.1021/ol800934r" @default.
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