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- W2949213249 abstract "A novel method is presented for the one-pot synthesis of substituted 3-(2-hydroxyethyl)- and 3-(3-hydroxypropyl)indoles (tryptophols and homotryptophols) from aryl hydrazines and silyl-protected ω-(hydroxyoalkyl)alkynes. Various tryptophol derivatives were prepared directly in good yield with excellent regioselectivity via a domino reaction sequence consisting of a titanium-catalyzed hydroamination of the alkyne, [3+3]-rearrangement of the resulting aryl hydrazone, and subsequent deprotection of the hydroxy group." @default.
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- W2949213249 date "2005-08-01" @default.
- W2949213249 modified "2023-10-18" @default.
- W2949213249 title "Convenient synthesis of tryptophols and tryptophol homologues by hydroamination of alkynes" @default.
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- W2949213249 doi "https://doi.org/10.1016/j.tet.2005.05.093" @default.
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