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• W2949217492 abstract "[reaction: see text] Various ferrocene-based organosilanols have been synthesized in four steps starting from achiral ferrocene carboxylic acid. Applying these novel planar-chiral ferrocenes as catalysts in asymmetric phenyl transfer reactions to substituted benzaldehydes afforded products with high enantiomeric excesses. The best result (91% ee) was achieved in the addition to p-chlorobenzaldehyde with organosilanol 2b, which has a tert-butyl substituent on the oxazoline ring and an isopropyl group on the silanol fragment." @default.
• W2949217492 created "2019-06-27" @default.
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• W2949217492 creator A5066779767 @default.
• W2949217492 creator A5086983143 @default.
• W2949217492 date "2005-03-01" @default.
• W2949217492 modified "2023-10-16" @default.
• W2949217492 title "Organosilanols as Catalysts in Asymmetric Aryl Transfer Reactions" @default.
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• W2949217492 doi "https://doi.org/10.1021/ol050242+" @default.
• W2949217492 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15787518" @default.
• W2949217492 hasPublicationYear "2005" @default.
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