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- W2949271960 abstract "cis- and trans-Oxazoline-5-carboxylates were synthesized efficiently from isopropyl trans-cinnamate utilizing the Sharpless AA reaction. trans-Oxazoline was much more reactive than the cis-isomer toward ring opening reactions. From ab initio molecular calculations, the cis-isomer was predicted to be less reactive than the trans-isomer by 2.7 kcal/mol. Both syn and anti acetylthio esters and anti diamino esters were synthesized from these cis- and trans-oxazoline-5-carboxylates." @default.
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- W2949271960 date "2000-04-14" @default.
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- W2949271960 title "Efficient Syntheses and Ring-Opening Reactions of <i>trans</i>- and <i>cis</i>-Oxazoline-5-carboxylates" @default.
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- W2949271960 doi "https://doi.org/10.1021/ol005681h" @default.
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